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Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter19: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 19.36QAP: From the proton NMR spectrum in Figure 19-44, deduce the structure of this hydrocarbon
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IR Spectrum
(quid film)
U
4000
wwwwwwww
9898
% of base peak
3000
43
91
40
80
13C NMR Spectrum
(50.0 MHz, CDCI, solution)
DEPT CH₂ CH, CH
proton decoupled
L
200
¹H NMR Spectrum
(200 MHz, CDCI, solution)
10
9
8
1715
2000
120
V (cm¹)
M
134
My
1600
160
m/e
7
160
200
J
120
6
800
0.0
Mass Spectrum 0.5
1.0
CgH100
1.56
280
1200
240
5
solvent
80
problem 9
UV spectrum
solvent: cyclohexane
7.90 mg/10 mis
path length:0.50 cm
300
4
absorbance
200
3
40
250
2
350
0 8 (ppm)
TMS
L
0
8 (ppm)
λ (nm)
1
1
Transcribed Image Text:IR Spectrum (quid film) U 4000 wwwwwwww 9898 % of base peak 3000 43 91 40 80 13C NMR Spectrum (50.0 MHz, CDCI, solution) DEPT CH₂ CH, CH proton decoupled L 200 ¹H NMR Spectrum (200 MHz, CDCI, solution) 10 9 8 1715 2000 120 V (cm¹) M 134 My 1600 160 m/e 7 160 200 J 120 6 800 0.0 Mass Spectrum 0.5 1.0 CgH100 1.56 280 1200 240 5 solvent 80 problem 9 UV spectrum solvent: cyclohexane 7.90 mg/10 mis path length:0.50 cm 300 4 absorbance 200 3 40 250 2 350 0 8 (ppm) TMS L 0 8 (ppm) λ (nm) 1 1
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