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- 4. From the appropriate raw materials and necessary chemical reagents; prepare phenylacetaldehyde by reaction of dithianes. Carry out the reaction mechanism for such an objective.3 Organic Chemistry, helppp with ALL PARTS(A&B) Consider the monoterpene linalool, a natural product used in the fragrance industry. When linalool (right panel) is treated with a strong protic acid in the presence of heat, 12 distinct products form. a. Given the initial structure of linalool, draw the structure of these 12 products b. Show the structure of the five intermediates that facilitate the formation of these 12 products and use arrow pushing to show how the intermediates form#20 B Draw structural formulas for all possible carbocations formed by the reaction of each alkene with HCl.
- 4. draw the structure of the organic product for each alcohol reacting with permanganate. Look on the internet for an explanation of why the tertiary alcohol in presence of KMnO4 might react. (hint may involve dehydration.) - methanol - ethanol - propanol - 2-methyl-2-propanolExplain the order of boiling points of the isomeric alcohols but an_1_ol boiling point of 118°C,but an_2_al boiling point of 99°C and 2_methylpropan_2_al boiling point 82°C Menthone and menthal are both isolated from mint ,explain why menthal is a solid at room temperature while menthone is a liquid at room temperature The boiling point of cis _but_2_ene is 3.7°C whereas that of trans_but_2_ene is 0.9°C explainHeating an alcohol with sulfuric acid is a good way to prepare a symmetrical ether such as diethyl ether. a. Explain why it is not a good way to prepare an unsymmetrical ether such as ethyl propyl ether. b. How would you synthesize ethyl propyl ether?
- The reaction of a nitrile with an alcohol in the presence of a strong acid forms an N-substituted amide. This reaction, known as the Ritter reaction, doesnot work with primary alcohols. a. Why does the Ritter reaction not work with primary alcohols? b. Provide an explanation for why an amide is less susceptible to nucleophilic attack than its corresponding ester.Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):1. Which compound is expected to have a higher melting point, 1-pentanol or 1-pentanal? Explain 2. Which compound is expected to be more soluble in water, propanal or butanal? Explain. 3. Why is acetyl chloride more reactive towards hydrolysis than ethyl acetate?
- 2-bromo-2-methylbutane undergoes hydrolysis reaction with water, H2O toform compound W. Compound X and compound Y are produced when 2-bromo-2-methylbutane undergoes elimination reaction with alcoholic ofsodium hydroxide, NaOH. (ii) What is the type of reaction involved in the formation of compound W? (iii) Identify the major product of the elimination reaction between compound Xand compound Y based on Zaitsev’s rule.KMnO4, warm, conc'd reacts with hept-1-ene to yield __________. CO2, hex-1-ene CO2, hexanoic acid Formic acid, pentanoic acid Ethanoic acid, pentanal Formic acid, hexanone1. Illustrate the Synthesis or Preparation of Benzoic Acid from the oxidation of Benzaldehyde with Tollen's reagent. Instruction: a.) Write the Correct Structural Formula of the Reactant/s b.) Write the formula of the specific Catalyst/s of the reaction c.) Predict the Product/s of the given reactions.