Predict the order of reactivity (and justify your prediction): (a) in cationic polymerization: styrene, p- methoxystyrene, p-chlorostyrene, p-methylstyrene; (b) in anionic polymerization: styrene, 2-vinylpyri- dine, 3-vinylpyridine, 4-vinylpyridine.

Predict the order of reactivity (and justify your prediction): (a) in cationic polymerization: styrene, p- methoxystyrene, p-chlorostyrene, p-methylstyrene; (b) in anionic polymerization: styrene, 2-vinylpyri- dine, 3-vinylpyridine, 4-vinylpyridine.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter31: Synthetic Polymers

Section31.1: Chain-growth Polymers

Problem 1P: Order the following monomers with respect to their expected reactivity toward cationic...

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Predict the order of reactivity (and justify your prediction): (a) in cationic polymerization: styrene, p-
methoxystyrene, p-chlorostyrene, p-methylstyrene; (b) in anionic polymerization: styrene, 2-vinylpyri-
dine, 3-vinylpyridine, 4-vinylpyridine.

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