Primary standard Secondary standard Endpoint equivalence point |||| ||| = = = III The point in a titration where the indicator changes color. A solution that has been standardized with a primary standard so that the exact concentration is known. A reactant that is stable and can be weighed so that the exact number of moles is known. The point in a titration where the mole ratios of the two reacting substances are the same as in the balanced equation. A solution of titrated acid.

Primary standard Secondary standard Endpoint equivalence point |||| ||| = = = III The point in a titration where the indicator changes color. A solution that has been standardized with a primary standard so that the exact concentration is known. A reactant that is stable and can be weighed so that the exact number of moles is known. The point in a titration where the mole ratios of the two reacting substances are the same as in the balanced equation. A solution of titrated acid.

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

ChapterA1: Evaluation Of Analytical Data

Section: Chapter Questions

Problem A1.22QAP

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00 mL of a diprotic acid primary standard solution was accurately prepared to a concentration of 0.1431 M. Three samples of this primary standard solution were used as samples in a titration to standardize an aqueous solution of sodium hydroxide, NaOH, which would be used as a titrant. Using the following table of data for the titration of the primary standard acid with NaOH, calculate the average concentration of NaOH. Trial # Volume of primary standard Initial titrant volume Final titrant volume 1 10.00 mL 8.21 mL 27.22 mL 2 10.00 mL 27.22 mL 46.23 mL 3 10.00 mL 30.28 mL 49.29 mL 0.1506 M 0.0753 M 0.0376 M 0.1431 M 0.0526 M
Sources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided TOPIC: Measured mass of the precipitate 1. Filter paper was dried prior to filtration. EX _____ ET TOPIC: Standardization of Titrant 2. Distilled water was not equilibrated to room temperature before the preparation of NaOH titrant. EX ______ ET TOPIC: Determination of Molar Concentration of each component (Double Indicator Titration) 3. No blank correction EX ______ ET
PS. Further values required for the solvings are give in the various situations below. (ANSWER) Situation: A community in a mountainous area of Bohol uses water collected from a nearby natural spring. A sample was submitted to a laboratory for the analysis of its total hardness. Required: SHOW YOUR COMPLETE CALCULATIONS. BASED ON THE IMAGE PROVIDED BELOW FOR THIS QUESTION: Calculate the amount of titrant used in each trial to reach endpoint. Report total hardness of the sample as mean ±sd. a. 250.0 mL of 500.0 ppm of CaCO3 solution from a primary standard (assume solvent is distilled water only). Answer : Mass of CaCO3 = 0.125 g b, The EDTA solution was standardized by titrating it with a 25.0 mL aliquot of the CaCO3 solution. How much of the titrant was consumed. Answer: Volume of EDTA consumed = 12.405 g c. Calculate the average titer (mg CaCO3/mL EDTA). Mass of CaCO3 in 25 mL CaCO3 solution: 0.0125 g Answer: 1.008 mg CaCO3/ mL EDTA
Distinguish the terms end point and equivalence point.
Sources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided TOPIC: Measured mass of the precipitate Question 4 Overignition which causes the conversion of BaSO4 precipitate to BaO. EX ___ ET Question 5 Precipitate was not washed thoroughly. Ex ___ ET TOPIC: Standardization of Titrant Question 6 Adding insufficient amount of titrant to reach acceptable endpoint color: EX ___ ET
If 500mL of 0.10M Ca2+ is mixed with 500mL of 0.10M SO42-, what mass of calcium sulfate will precipitate? Ksp for CaSO4 is 2.40 • 10-5. express answer to 3 significant figures. And include units.
SCE students measured the concentration of HCl in a solution by titrating with different indicators to find the end point.Indicator Mean HCl concentration (M)(± standard deviation)Number of measurementsBromothymol blue 0.09565 ± 0.00225 28Methyl red 0.08686 ± 0.00098 18Bromocresol green 0.08641 ± 0.00113 29Is the difference between indicators 1 and 2 significant at the 95% confidence level? Answer the same question for indicators 2 and 3
The chloride in the sample is to be determined gravimetrically by precipitating and weighing AgCl. What weight in grams of sample should be taken so that the percentage of Cl is obtained by simply multiplying the weight of the AgCl precipitate by 10?
Write an objective of separation of a mixture by extraction
How is Qsp affected when adding in excess reagent during a precipitation?
A local company sent you their green alternative for window cleaner to be tested for percent (w/v) acetic acid content. For your experiment, you first standardized your NaOH titrant with 0.8053 g of (99.80 % purity) KHP. You used 40.60 mL of NaOH for your standardization. After that you then analyzed a 10.00 mL sample and found that you needed 43.20 mL NaOH to reach the end point. Summary of results: Standardization Sample analysis KHP Weight (g) 0.8053 g Volume of sample 50.00 mL Purity 99.80% NaOH (mL) used 33.20 mL NaOH (mL) used 40.60 mL Determine the following: Molarity of NaOH % (w/v) acetic acid
Sources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided. TOPIC: Measured mass of the precipitate 1. Overignition which causes the conversion of BaSO4 precipitate to BaO. EX _____ ET2. Precipitate was not washed thoroughly. Ex _____ ET TOPIC: Standardization of Titrant 3.Distilled water was not equilibrated to room temperature before the preparation of NaOH titrant. EX _______ ET