PROBLEM: A key step in the production of sulfuric acid is the oxidation of SO₂(g) to SO3(g): 2SO₂(g) + O₂(g) → 2SO3(g) At 298 K, AG = -141.6 kJ; AH = -198.4 kJ; and AS = -187.9 J/K (a) Use the data to decide if this reaction is spontaneous at 25°C, and predict how AG will change with increasing T. (b) Assuming AH and AS are constant with increasing T, is the reaction spontaneous at 900.° C?

Chemistry: Matter and Change
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ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
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Chapter15: Energy And Chemical Change
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PROBLEM: A key step in the production of sulfuric acid is the oxidation
of SO₂(g) to SO3(g):
2SO₂(g) + O₂(g) → 2SO3(g)
At 298 K, AG = -141.6 kJ; AH = -198.4 kJ; and AS = -187.9 J/K
(a) Use the data to decide if this reaction is spontaneous at 25°C, and
predict how AG will change with increasing T.
(b) Assuming AH and AS are constant with increasing T, is the
reaction spontaneous at 900.° C?
PROBLEM:
ΔΗ = 58.1 kJ
At 25°C (298 K), the reduction of copper(1) oxide is
nonspontaneous AG = 8.9 kJ). Calculate the temperature
at which the reaction becomes spontaneous.
AS = 0.165 kJ/K
Transcribed Image Text:PROBLEM: A key step in the production of sulfuric acid is the oxidation of SO₂(g) to SO3(g): 2SO₂(g) + O₂(g) → 2SO3(g) At 298 K, AG = -141.6 kJ; AH = -198.4 kJ; and AS = -187.9 J/K (a) Use the data to decide if this reaction is spontaneous at 25°C, and predict how AG will change with increasing T. (b) Assuming AH and AS are constant with increasing T, is the reaction spontaneous at 900.° C? PROBLEM: ΔΗ = 58.1 kJ At 25°C (298 K), the reduction of copper(1) oxide is nonspontaneous AG = 8.9 kJ). Calculate the temperature at which the reaction becomes spontaneous. AS = 0.165 kJ/K
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