PROBLEM: Choose the member with the higher entropy in each of thefollowing pairs, and justify your choice [assume constanttemperature, except in part (e)]:(a) 1 mol of SO₂(g) or 1 mol of SO3(g)(b)1 mol of CO₂ (s) or 1 mol of CO₂(g)3 mol of O₂(g) or 2 mol of O3(g)(c)(d)1 mol of KBr(s) or 1 mol of KBr(aq)seawater at 2°C or at 23°C(e)(f) 1 mol of CF₂(g) or 1 mol of CCl4 (9)PROBLEM: A key step in the production of sulfuric acid is the oxidationof SO₂(g) to SO3(g):2SO₂(g) + O₂(g) → 2SO3(g)At 298 K, AG = -141.6 kJ; AH = -198.4 kJ; and AS = -187.9 J/K(a) Use the data to decide if this reaction is spontaneous at 25°C, andpredict how AG will change with increasing T.(b) Assuming AH and AS are constant with increasing T, is thereaction spontaneous at 900.° C?PROBLEM:ΔΗ = 58.1 kJAt 25°C (298 K), the reduction of copper(1) oxide isnonspontaneous AG = 8.9 kJ). Calculate the temperatureat which the reaction becomes spontaneous.AS = 0.165 kJ/K

Answered: Image /qna-images/answer/b9ae4d8d-6e7c-43ac-a289-b52c16be0ccf.jpg

PROBLEM: Choose the member with the higher entropy in each of the following pairs, and justify your choice [assume constant temperature, except in part (e)]: (a) 1 mol of SO₂(g) or 1 mol of SO3(g) (b) 1 mol of CO₂(s) or 1 mol of CO₂(g) (c) 3 mol of O₂(g) or 2 mol of O3(g) (d) 1 mol of KBr(s) or 1 mol of KBr(aq) seawater at 2°C or at 23°C (e) (f) 1 mol of CF4(g) or 1 mol of CCl4(9)

PROBLEM: Choose the member with the higher entropy in each of the following pairs, and justify your choice [assume constant temperature, except in part (e)]: (a) 1 mol of SO₂(g) or 1 mol of SO3(g) (b) 1 mol of CO₂(s) or 1 mol of CO₂(g) (c) 3 mol of O₂(g) or 2 mol of O3(g) (d) 1 mol of KBr(s) or 1 mol of KBr(aq) seawater at 2°C or at 23°C (e) (f) 1 mol of CF4(g) or 1 mol of CCl4(9)

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter3: The Second And Third Laws Of Thermodynamics

Section: Chapter Questions

Problem 3.51E: Order the following substances in order of increasing entropy: NaCl(solid), C(graphite), C(diamond),...

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