Propanoic acid and methyl ethanoate are constitutional isomers. (b) (c) CH3 (d) CH₂ OH propanoic acid Show how to distinguish between them by IR spectroscopy. (Use the Appendix.) (a) Which IR bands would one expect for propanoic acid? 1200-1250 cm 1375-1450 cm 1450-1475 cm -1 -1 -1 1 1630-1820 cm7 -1 1200-1250 cm -1 1375-1450 cm7 1450-1475 cm 1630-1820 cm I 1 1 1 1200-1250 cm 1375-1450 cm 1450-1475 cm 1 1630-1820 cm7 -1 CH3 methyl ethanoate Which IR bands would one expect for methyl ethanoate? 1 If the IR spectrum shows a which band at 1780 cm isomer is it? 1700-1725 cm -1 1735-1800 cm 2720 cm 2500-3300 cm 2720 cm -1 1700-1725 cm 1735-1800 cm -1 2500-3300 cm -1 CH3 Which IR bands are unique to, i.e. not shared between, the two sets? 2720 cm -1 1700-1725 cm 1735-1800 cm -1 2500-3300 cm 1 -1 -1 1 -1 1

Macroscale and Microscale Organic Experiments
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ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
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Chapter19: Alkenes From Alcohols: Cyclohexene From Cyclohexanol
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Propanoic acid and methyl ethanoate are constitutional isomers.
(c)
оооо
(d)
CH3
оооо
CH₂ OH
Show how to distinguish between them by IR spectroscopy. (Use the Appendix.)
(a) Which IR bands would one expect for propanoic acid?
propanoic acid
оооо
1200-1250 cm
1375 1450 cm
1450 1475 cm
1630-1820 cm
-1
1200-1250 cm
1375 1450 cm
1450-1475 cm
1630-1820 cm
1375 1450 cm
-1
-1
-1
-1
1200-1250 cm
(b) Which IR bands would one expect for methyl ethanoate?
-1
-1
1450 1475 cm
-1
-1
1630-1820 cm
-1
00000000
−1
CH₂-C
0000
methyl ethanoate
If the IR spectrum shows a
band at 1780 cm-¹, which
isomer is it?
1700-1725 cm
1735-1800 cm
2720 cm
-1
2500-3300 cm
2720 cm
Which IR bands are unique to, i.e. not shared between, the two sets?
-1
1700 1725 cm
2500-3300 cm
-1
CH3
1735-1800 cm
-1
-1
-1
2720 cm
-1
2500-3300 cm
-1
1700-1725 cm
-1
1735-1800 cm
-1
-1
-1
Transcribed Image Text:Propanoic acid and methyl ethanoate are constitutional isomers. (c) оооо (d) CH3 оооо CH₂ OH Show how to distinguish between them by IR spectroscopy. (Use the Appendix.) (a) Which IR bands would one expect for propanoic acid? propanoic acid оооо 1200-1250 cm 1375 1450 cm 1450 1475 cm 1630-1820 cm -1 1200-1250 cm 1375 1450 cm 1450-1475 cm 1630-1820 cm 1375 1450 cm -1 -1 -1 -1 1200-1250 cm (b) Which IR bands would one expect for methyl ethanoate? -1 -1 1450 1475 cm -1 -1 1630-1820 cm -1 00000000 −1 CH₂-C 0000 methyl ethanoate If the IR spectrum shows a band at 1780 cm-¹, which isomer is it? 1700-1725 cm 1735-1800 cm 2720 cm -1 2500-3300 cm 2720 cm Which IR bands are unique to, i.e. not shared between, the two sets? -1 1700 1725 cm 2500-3300 cm -1 CH3 1735-1800 cm -1 -1 -1 2720 cm -1 2500-3300 cm -1 1700-1725 cm -1 1735-1800 cm -1 -1 -1
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