Consider the below molecule. Please use the dropdown menus to complete the table by ranking the indicated hydrogen atoms from STRONGEST to WEAKEST acid. OH C STRONGEST Acid [Select] H A H B Intermediate [Select] WEAKEST Acid [Select]

Consider the below molecule. Please use the dropdown menus to complete the table by ranking the indicated hydrogen atoms from STRONGEST to WEAKEST acid. OH C STRONGEST Acid [Select] H A H B Intermediate [Select] WEAKEST Acid [Select]

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter20: Acidity And Pka Of Phenols

Section: Chapter Questions

Problem 7E

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Arrhenius acid act as a good electrolyte as it dissociates to its respective ions in the aqueous solutions. Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red.

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Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with.

Question

Consider the below molecule. Please use the dropdown menus to
complete the table by ranking the indicated hydrogen atoms from
STRONGEST to WEAKEST acid.
OH
C
STRONGEST Acid
[Select]
A
H
B
Intermediate
[Select]
WEAKEST Acid
[Select]

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For the previous four questions, label each molecule that appears in the question or your answer asstrong acid, strong base, weak acid, or weak base.
(E) Label each of the following as strong acid, strong base, or neither.
The following are equivalent ways of asking about the acidity of an H atom: • What is the most acidic H on the molecule? • Which H is associated with the published pKa value? • Which H on the molecule is easiest to remove? • Which H on the molecule takes the least energy to remove? • Which bond to an H is most polarized? • For which H atom is removal least uphill in energy? • Which bond to an H atom, when broken, results in the lowest PE conjugate base? We will often find the last of these questions is easiest to answer. To do this, find all the different Hatoms on the molecule, and draw all possible conjugate bases.Only the lowest-energy one is the “real” conjugate base. Identify this structure, and you have found the most acidic H. Use this strategy to find the most acidic H on each of the following molecules. Note: Each structure hasat least three different kinds of H’s, so draw at least three unique conjugate bases for each.
When a proton becomes bonded to diethyl ether, by way of one of the unshared electron pairs on the oxygen atom, the result is In this structure the oxygen atom owns one electron from each of ____ shared pairs and two electrons from ____ unshared pair. The total number of electrons that belong to oxygen is ____. The formal charge on oxygen is ____. The correct Lewis structure for the conjugate acid of diethyl ether is ___________________________
Summarize the relationship between pKa and base strength by completing the followingsentences: a. For a given base, the higher the pKa of its conjugate acid, the stronger or weaker the base. b. For a given base, the lower the pKa of its conjugate acid, the stronger or weaker the base.
Complete the equation for the reaction between each Lewis acid-base pair. In each equation, label which starting material is the Lewis acid and which is the Lewis base; use curved arrows to show the flow of electrons in each reaction. In doing this problem, it is essential that you show valence electrons for all atoms participating in each reaction. (a) (b) (c) (d)