Propose structural formulas for compounds A and B and specify the configuration of compound B. 1. Og C,H10 2. (CH3),S 200°C + CH,=CH2 C,H1,02 (A) (В)
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- On being heated with a solution of sodium ethoxide in ethanol, compound A (C7H15Br) yielded a mixture of two alkenes B and C, each having the molecular formula C7H14. Catalytic hydrogenation of the major isomer B or the minor isomer C gave only 3-ethylpentane. Suggest structures for compounds A, B, and C consistent with these observations.Using benzene and any necessary organic or inorganic reagents, suggest efficient syntheses of (a) Isobutylbenzene, C6H5CH2CH(CH3)2 (b) (2,2-Dimethylpropyl)benzene, C6H5CH2C(CH3)3An unknown hydrocarbon G, whose formula is C16H26 contains two triple bonds. Ozonolysis followed by reduction with (CH3)2S gave CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. Suggest a reasonable structure for compound G.
- Aspirin, or 2-acetoxybenzoic acid, (C9H8O4) is often synthesised from salicylic acid.(i) Sketch and discuss any changes in the number of possible structural conformations ofaspirin relative to those of salicylic acid. (ii) Re-draw the structure predicted to be the lowest energy conformation of aspirin,indicating any expected stabilising and destabilising interactions. Justify your choice.Birch reduction of 2-methoxynaphthalene gave a mixture of two isomeric compounds, each having the molecular formula C11H14O. Suggest reasonable structures for these compounds.Using the normal/primary isomer of C4H10O, treat it with conc.H2SO4 and heat to produce A. Treatment of A with HCl/H2O gives B and with cold KMnO4/ OH- gives C . Give the name and structures of A, B and C Treatment of A with Hot KMnO4/OH- gives D followed by acidification of the mixture to give E. What is D and E ?
- On being heated with a solution of sodium ethoxide in ethanol, compound A (C7H15Br) produced a mixture of two alkenes B and C, each of which had the molecular formula C7H14. Catalytic hydrogenation of major isomer B or minor isomer C gave only 3-ethylpentane. Suggest structures and mechanisms for compounds A, B, and C consistent with these observations.Compound X has molecular formula C5H10. In the presence of a metal catalyst, compound X reacts with one equivalent of molecular hydrogen to yield 2-methylbutane. (1) Suggest three possible structures for compound X. (2) Hydroboration-oxidation of compound X yields a product with no chirality centers. Identify the structure of compound X.The German chemist Wilhelm Kӧrner (1839-1925) observed in 1974 that each of the three isomers of dibromobenzene, A, B, and C, gave a different number of tribromobenzenes upon further bromination, allowing him to assign their respective structures. Try to do the same and assign structures to A, B, and C based on the following results: A gives two tribromobenzenes in comparable amounts B gives three tribromobenzenes, one of them in minor quantities C gives only one tribromobenzene
- 1,2,3,4,5-Pentafluoro-6-nitrobenzene reacts readily with sodium methoxide in methanol at room temperature to yield two major products, each having the molecular formula C7H3F4NO3. Suggest reasonable structures for these two compounds.Two moles of organic compound ‘A’ on treatment with a strong base gives two compounds ‘B’ and ‘C’. Compound ‘B’ on dehydrogenation with Cu gives ‘A’ while acidification of ‘C’ yields carboxylic acid ‘D’ with molecular formula of CH2O2. Identify the compounds A, B, C and D and write all chemical reactions involved.A compound C4H11N is known from its reactivity andspectroscopic properties to have no hydrogen atomsattached directly to the nitrogen atom. Write all structuralformulas consistent with this information