Provide a stepwise synthesis for benzyl chloride to benzyl alcohol with reagents Na2CO3 and H2O (including arrow-pushing mechanisms)  Kindly show all the arrow push

Q: Provide a stepwise synthesis for benzyl chloride to benzyl alcohol with reagents Na2CO3 and…

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Q: (a) Aniline is oxidized and then resulting product is boiled with Conc. HNO3 and conc. H2S04C (b)…

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Q: A carbonyl compound on reaction with lodine in presence of sodium hydroxide followed by hydrolysis…

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Q: The ionones are fragrant substances present in the scent of iris and are used in perfume. A mixture…

A: Ionones are a group of compounds that are cyclic in nature and they have a specific aroma in their…

Q: Devise a synthesis of benzocaine, ethyl p-aminobenzoate (H2NC6H4CO2CH2CH3), from benzene, organic…

A: A synthesis of benzocaine (ethyl p-aminobenzoate) can be shown as follows, First benzene is…

Q: When 1-butanol is treated with conc. H2SO4 and heat .A product 'A'  is formed from the reaction.…

A: When alcohol reacts with the acid H2SO4, the alcohol undergoes dehydration reaction where the water…

Q: Devise a synthesis of the ketone hexan-3-one, CH3CH2COCH2CH2CH3, from CH3CH2Br as the only organic…

A: Ethyl bromide react with magnesium in the presence of ether results in the formation of ethyl…

Q: Propose a mechanism for the steam hydrolysis of pulegone to the compounds shown.

A: Hydrolysis – Addition of water in a given molecule  is called hydrolysis Hydrolysis is simply the…

Q: Phenylacetone can form two different enols.(a) Show the structures of these enols.(b) Predict which…

A: Enol is a structure that has a double bond with a hydroxyl group attached to one of the olefinic…

Q: 1. 2. a. b. Provide the major organic product of the following reactions. a. b. 1. Mg, ether 1. Mg,…

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Q: Propose single-step and multistep syntheses of acid derivatives from compoundscontaining other…

A: Since you have posted a question with multiple questions, we will solve first question for you. To…

Q: Identify products A and B from the given 1H NMR data. Treatment of CH2=CHCOCH3 with one equivalent…

A: Addition of a molecule over a double bond is called addition reaction. After addition of HCl, three…

Q: Compound D contains nitrogen and produces a gas upon heating with aqueous NaOH. When the resulting…

A: We have to give the structures of D, E, and F. Also, we have to give the synthesis route without the…

Q: Provide a stepwise synthesis for sodium benzoate to benzoic acid with reagents HCl (including…

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Q: 6. Provide a synthesis for the molecule below showing all reagents and synthetic intermedate „CH3…

A: According to the question, we need to convert ethylbenzene to 4-chloro ethylbenzene.

Q: 17. (5@; 20) Synthesis. Beginning with alcohols of FOUR carbons or fewer, OUTLINE syntheses of the…

A: There are many mechanisms in organic chemistry such as nucleophilic substitution, nucleophilic…

Q: a) 1-phenypentane b) p-bromobenzene sulfonic acid

A: Using Friedel craft alkylation and bromination we can form the given product. Product formation…

Q: When Ethanoic is heated with NH3 and resulting product reacts with benzoylchloride.

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Q: Propose routes to a)propylmagnesium bromide b)propylzinc bromide c)propyllithium and d)dipropylzinc…

A: Note  - Since you have asked a question with multiple sub-parts, we are bound to solve only the…

Q: Suggest a synthesis of the following compound by Claisen or Dieckmann condensations. Show all…

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Q: a) The scheme below shows the synthesis of a natural product: MgBr- он B ore CHO CHO Suggest…

A: In the sequence of the reaction in the first step addition of Grignard reagent on the carbonyl group…

Q: Suggest the most appropriate method for each of the following laboratory syntheses. Ineach case,…

A: Chromium(VI) based reagents have been extensively used as oxidizing agents in synthetic organic…

Q: 1. Beginning with the correct organic halide and benzophenone (C6HS C(0)C6H5) show how one would…

A: Detail mechanistic pathway is given below

Q: Provide a stepwise synthesis for benzyl alcohol to sodium benzoate with reagents KMnO4 and NaOH…

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Q: When cis-2-decalone is dissolved in ether containing a trace of HCI, an equilibrium is established…

A: Organic chemistry involves reactions of organic molecules. The reactions can show changes in cis and…

Q: Show how you would synthesize the following compounds, starting with benzene or toluene and any…

A: a) p-aminobenzoic acid Toluene on nitration gives para-nitro toluene. Para-nitro toluene on further…

Q: Identify products A and B from the given 1H NMR data. a.Treatment of CH2=CHCOCH3 with one equivalent…

A: a. The given compound is CH2=CHCOCH3.  It reacts with one equivalent of HCl to form compound A.  The…

Q: Suggest a synthesis of the following compound by Claisen or Dieckmann condensations. Show all…

A: 1. Claisen condensation :  Ester in presence of base like NaOEt ( sodium ethoxide) gives followed…

Q: Devise a synthesis of the following compound. You may use HC=CH, ethylene oxide, and alkyl halides…

A: Acetylene (C2H2) contains two acidic hydrogens in presence of strong base like NaH it gives…

Q: (a) Suggest a synthesis for the following molecules starting with benzene and any other necessary…

A: -NH2=ortho para director -NO2=meta director  -Cl is ortho para director.

Q: Identify products A and B from the given 1H NMR data.a. Treatment of CH2 = CHCOCH3 with one…

A: (a). The given compound is CH2=CHCOCH3.  It reacts with one equivalent of HCl to form compound A.…

Q: B-Damascenone belongs to a family of fragrant natural products called rose ketones that have been…

A: MCPBA is use for the epoxidation of alkene. MCPBA is electron deficient compound this it selectively…

Q: 9. The synthesis of the gastric antisecretory rioprostil requieres the synthesis of alcohol X: a.…

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Q: Outline the synthesis of each compound from benzene, toluene or alcohol of a smaller carbon and any…

A: Applying concept of reagents and reaction.

Q: Predict the products of reactions of ethers and epoxides, including the following:(a) Cleavage and…

A: (a) Cleavage and autoxidation of ethers The cleavage of C-O bond by strong acids is the most common…

Q: Compound A is an optically active alcohol. Treatment with chromic acid converts A intoa ketone, B.…

A: Chromic acid is an oxidising agent which converts alcohols to either aldehyde or ketone. Actually,…

Q: Devise efficient laboratory syntheses of ethers and epoxides, including the following:(a) The…

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Q: Compound A reacts with 1 molar equivalent(s) of hydrogen upon catalytic hydrogenation. A undergoes…

A: Hydrogenation is defined as the chemical reaction between molecular hydrogen and the another element…

Q: Suggest a synthesis of the following from benzene. You may use any aditional reagents as necessary.…

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Q: b) Pyrrole and indole both react with the reagents shown below to give compounds E and F…

A: Pyrrole and indole both are undergoing electrophilic substitution reaction.  We have to tell the…

Q: NH

A: The following transformation needs to be carried out using various reagents.

Q: (a) 1-methylcyclopentene B can be prepared by an intramolecular Wittig reaction from A. Propose a…

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Q: Show how you would synthesize the following compounds, starting with benzene or toluene and any…

A: SOLUTION: Step 1: Toluene on nitration gives para-nitro toluene. Para-nitro toluene on further…

Q: Show and explain reagents and expiramental conditions to synthesize each compound from 1- propanol.

A: (a) 1-propanol transforms to prop-1-ene in presence of acid and heat. (b) Prop-1-ene transforms to…

Q: Provide a stepwise synthesis for benzyl alcohol to sodium benzoate with reagents KMnO4 and NaOH

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Q: For each compound, show the products obtained from ozonolysis, followed by treatment with dimethyl…

A: Since you have posted question with multiple sub-parts, we are entitled to answer the first three.

Q: A carbonyl compound with an a hydrogen rapidly equilibrates with its corresponding enol. Give the…

A: The question is based on the concept of isomerism. keto enol isomerism is a form of tautomerism in…

Q: The last step in the synthesis of β-vetivone, a major constituent of vetiver, a perennial grass…

A: Vetivone is an organic compound which is derived from three isoprene units and belongs to the class…

Q: Compelling evidence for the existence of a tetrahedral intermediate innucleophilic acyl substitution…

A: In nucleophilic acyl substitution reaction, the nucleophile gets into position of leaving group.

Q: Compound B c) Identify and indicate the major and minor product(s) formed if compound B undergo…

A: Chlorination of alkanes follows free radical substitution mechanism.

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.