Provide the systematic name for each of the following isomeric esters with the chemical formula C-H₁20₂. (Be sure to indicate double bond stereochemistry using (E)/(Z) notation. Indicate stereochemistry in rings with the terms cis or trans. It is not necessary to use italics in writing compound names.) ball & stick + labels ball & stick + labels ball & stick + labels 12
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- The name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.Draw the products formed by the following acid-base reaction without consideration of the equilibrium position: You do not have to consider stereochemistry. You should include all products. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Separate structures with + signs from the drop-down menu.help me please Please fill in the reagents,intermediates, and/or products of the following reactions. all the reactions shall be covered in Chapter 12-15 from Organic Chemistry, 6th Edition by Marc Loudon and Jim Parise.
- Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. Use the wedge/hash bond tools to indicate stereochemistry where it exists. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after aqueous workup. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.The compound whose structure is shown here is acetyl acetone. It exists in two forms:the enol form and the keto form The molecule reacts with OH–to form an anion, [CH3COCHCOCH3] (often abbreviatedacac–for acetylacetonate ion). One or the most interesting aspects of this anion is thatone or more of them can react with transition metal cations to give stable, highlycolored compounds (a) Are the keto and enol forms of acetylacetone resonance forms? Explain youranswer.(b) What is the hybridization or each atom (except H) in the enol form? What changesin hybridization occur when it is transformed into the keto form?(c) What are the electron-pair geometry and molecular geometry around each C atomin the keto and enol forms? What changes in geometry occur when the keto formchanges to the enol form?(d) Draw three possible resonance structures for the acac–ion.(e) Is cis-trans isomerism possible in either the enol or the keto form of acetylacetone?(f) Is the enol form of acetylacetone polar?…1-pentanol + NaBr/H2SO4 -> 1-bromopentane Is this substitution reaction reversible? In other words, would one expect to obtain an equilibrium mixture of the alcohol and bromoalkene at the end of the reaction of would one expect this reaction to go to completion? Justify your answer?
- On the line drawn below, provide the systematic (IUPAC) name for the following structure. Be sure to include stereochemistry (R/S, cis-trans, or E/Z) when appropriate.Read these directions carefully. For the reaction of 3-methyl-1-propene with Cl2 and H2O shown below, fill in the details of the mechanism. Draw the appropriate chemical structures and use an arrow to show how pairs of electrons are moved to make and break bonds during the reaction. Be sure to write all lone pairs of electrons and all formal charges. Finally, in the boxes provided by the arrows, write which kind of mechanistic element is being indicated, such as "make a bond", "add a proton", etc.Draw the structure of the expected organic produect formed in the following reactions including correct stereochemistry; if the product is racemic indicate this by either drawing both isomers or drawing one and writing racemic. Assume all reagent are present in excess unless otherwise noted. If no reaction occurs, state "No Reaction".
- Reaction of -pinene with borane followed by treatment of the resulting trialkylborane with alkaline hydrogen peroxide gives the following alcohol. Of the four possible cis,trans isomers, one is formed in over 85% yield. (a) Draw structural formulas for the four possible cis,trans isomers of the bicyclic alcohol. (b) Which is the structure of the isomer formed in 85% yield? How do you account for its formation? Create a model to help you make this prediction.Give the organic product(s) formed in each of the following reactions. When necessary, draw a 3D representation for the product molecule showing its correct configuration.Give the IUPAC name of the 1,4-addition product of the reaction between 2-methylpenta-1,3-diene with HCl. No need to specify configuration/isomerism. These are reagents that seek a positive center. What is the IUPAC name of the product between the smallest ring that can form a stable cycloalkyne and hydrogen gas in the presence of palladium in calcium carbonate?