Q.30. Calculate the heat of combustion AH,°, 298K of solid oxalic acid (C2H2O4, s) at 25 °C and atmospheric pressure, using the standard molar enthalpies of formation. 1) Write the equation of this reaction and calculate, using the data, its standard enthalpy at 298K. 2) Explain why the standard enthalpy of formation of gaseous oxygen is equal to zero? (Explain in one sentence only) Given: Standard molar enthalpies of formation at 298.15K Substance and State A¢H® (kJ/mol) CH2O4(s) CH2O4(g) CO2(g) CO2(aq) H2O(g) H2O(1) O2(g) -829.9 -731.8 -393 -413.26 -241.8 -285.2
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
- Calculate the heat of combustion ΔHr°, 298K of solid oxalic acid (C2H2O4, s) at 25 °C and atmospheric pressure, using the standard molar enthalpies of formation.
- Write the equation of this reaction and calculate, using the data, its standard enthalpy at 298K.
- Explain why the standard enthalpy of formation of gaseous oxygen is equal to zero? (Explain in one sentence only)
Given:
Standard molar enthalpies of formation at 298.15K
|
Substance and State |
ΔfH0 (kJ/mol) |
|
C2H2O4(s) |
-829.9 |
|
C2H2O4(g) |
-731.8 |
|
CO2(g) |
-393 |
|
CO2(aq) |
-413.26 |
|
H2O(g) |
-241.8 |
|
H2O(l) |
-285.2 |
|
O2(g) |
0 |
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