Q1) Each of the following IR spectra is associated with one of the compounds below. Identify the compound associated with each spectrum. Justify your Answer O=C=N, vinyl acetate ethyl propiolate ethyl isocyanatoacetate A в MCRONS NCOLET 2SK FTR 25 26 27 2a 5 17 1 4000 300 3400 200 3000 2800 2600 2400 2200 2000 1800 100 1400 1200 1000 WAVENUMBERS

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 12VC
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Q1) Each of the following IR spectra is associated with one of the compounds below. Identify the compound associated with each spectrum. Justify your Answer

MICRONS
NICOLET 20SX FT-IR
25
100
2.7 2.8 2,9 3
15
16 17 18 19
21 22
2.6
3.5
4.5
55
6
10
11
12 13
14
90
05
80
f0.1
70
0.2
60
50
40
104
30
20
0.7
10
1.0
3800 3600 3400 3200
3000 2800 2600
2400 2200
1600
WAVENUMBERS
20
450
4000
2000
1800
1400
1200
1000
800
600
MICRONS
NICOLET 20SX FT-IR
14 15 16 17 18 19 21 22
2.5
100
2.6 2.7 2.8 2.9 3
3.5
4.5
5.5
6
10
11
12
13
90
80
0.1
70
0.2
60
50
-0.3
40
F0.4
os
30
0.6
20
0.7
10
1.0
20
4000
3800
3600
3400
3200
3000
2800
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
600
450
WAVENUMBERS
Transcribed Image Text:MICRONS NICOLET 20SX FT-IR 25 100 2.7 2.8 2,9 3 15 16 17 18 19 21 22 2.6 3.5 4.5 55 6 10 11 12 13 14 90 05 80 f0.1 70 0.2 60 50 40 104 30 20 0.7 10 1.0 3800 3600 3400 3200 3000 2800 2600 2400 2200 1600 WAVENUMBERS 20 450 4000 2000 1800 1400 1200 1000 800 600 MICRONS NICOLET 20SX FT-IR 14 15 16 17 18 19 21 22 2.5 100 2.6 2.7 2.8 2.9 3 3.5 4.5 5.5 6 10 11 12 13 90 80 0.1 70 0.2 60 50 -0.3 40 F0.4 os 30 0.6 20 0.7 10 1.0 20 4000 3800 3600 3400 3200 3000 2800 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 600 450 WAVENUMBERS
Q1) Each of the following IR spectra is associated with one of the compounds below. Identify
the compound associated with each spectrum. Justify your Answer
O=C=N
vinyl acetate
ethyl propiolate
ethyl isocyanatoacetate
A
MICRONS
NICOLET 20SX FT-IR
21 22
2.5
100
2.6 2.7 2.8 2.9 3
3.5
5.5
9
12
13
14
15
16 17 18 19
90
06
80
0.1
70
02
60
50
0.3
40
0.4
0.5
30
0.6
20
0.7
0.8
0.9
10
1.0
20
4000
3800
3600
3400
3200
3000
2800
2600
2400
2200
2000
1800
1600
1400
1200
1000
B00
600
450
WAVENUMBERS
Transcribed Image Text:Q1) Each of the following IR spectra is associated with one of the compounds below. Identify the compound associated with each spectrum. Justify your Answer O=C=N vinyl acetate ethyl propiolate ethyl isocyanatoacetate A MICRONS NICOLET 20SX FT-IR 21 22 2.5 100 2.6 2.7 2.8 2.9 3 3.5 5.5 9 12 13 14 15 16 17 18 19 90 06 80 0.1 70 02 60 50 0.3 40 0.4 0.5 30 0.6 20 0.7 0.8 0.9 10 1.0 20 4000 3800 3600 3400 3200 3000 2800 2600 2400 2200 2000 1800 1600 1400 1200 1000 B00 600 450 WAVENUMBERS
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