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Xi 931 11:18
4G
K/s
First exam REF..pdf
First exam
Chemistry
Refinary branch
Q1A: Find the four quantum number for
P15.
B: Calculate equivalent weight for H3PO4.
Q2 :Calculate [OH] for a0.75 liter solution
containing (5.35)gm of NH,CI Ammonium
chloride,know that K,(NH3)=2*10°.
Q3:Calculate the weight fraction of methyl
alcohol for a solution containing 27.5 gm
of methyl alcohol and 175 ml of
water(suppose the density of water=1
gm\ml)
Awt: H=1 ,P=30 ,0=16 ,N=14, Cl=35.
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Solved in 2 steps
- Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.A 0.1 M solution of acid was used to titrate 10 ml of 0.1 M solution of alkali and thefollowing volumes of acid were recorded: 9.88 10.18 10.23 10.39 10.21 Calculate the 95% confidence limits of the mean and use them to decide whetherthere is any evidence of systematic error.Calcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)
- A 350.00 mL solution of 0.00265 M A3B4 is added to a 280.00 mL solution of 0.00205 M C3D2. What is pQsp for A3D4?1.065g of MgO (Analyte) of 84.74% were treated w/ 50ml of 1.02N H2SO4 (Acidic Titrant), and 48.28 mL of NaOH (Base Titrant) 1.103N concentration MW of analyte: 40Meq of analyte: 0.02NaOH vol: 48.28 Compute for the meq weight consumed by the acidic titrant (g-meq)a) What mass of Fe(NH4)2(SO4)2•2H2O(s) is required to prepare a 500 mL solution containing 100 ppm (m:v) in Fe? b) Using this stock solution, what aliquot must be used to prepare calibration solutions, 100 mL volume, of the following concentrations: 0.100 ppm, 0.500 ppm, 2.00 ppm, 4.00 ppm, and 7.00 ppm.
- Hexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.How many grams of CaF2 (molar mass 78.077) will dissolve in 250 mL of 0.20 M NaF solution? The Ksp for CaF2 is 3.8904e-11.In the standardi zation of HCl using pure anhydrou s sodium carbonate as primarystandard for methy l orange as indica tor , 1.0 mL HCl was found to be equiva lent to 0.05gof sodium carbonate (MW =106). The no rmality of HCl is
- 5.00 mL of stock solution is diluted to 25.00 mL, producing solution ALPHA. 10.00 mL of solution ALPHA is diluted to 25.00 mL, resulting in solution BETA. 10.00 mL of solution BETA is then diluted to 25.00 mL, producing solution GAMMA. dilution factor for ALPHA from stock solution = 0.167 dilution factor for BETA from ALPHA solution = 0.0476 part c and d?One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?A sodium thiosulfate solution can be standardized by using it to titrate the iodine liberated by the action of excess KI on a known weight of primary standard K2Cr2O7: Cr2O72- + 6I- + 14H+ → 2 Cr3+ + 3I2 + 7H2O I2 + 2S2O32- → 2I- + S4O62- Calculate the molar concentration of the sodium thiosulfate solution if 31.47 mL of this solution were required to titrate a sample prepared using 0.2177 g pure K2Cr2O7.