Q2/ A) The following reaction was monitored as a function of time: A → B+CA plot of In[A] versus time yields a straight line with slope=- 0.0045 s1) What is the value of the rate constant, k, for this reaction at this temperature?2) What is the half life?3) If the initial concentration of A is 0.250 mol.L' what is the concentration of A after 225 s?B)4A2+4B2 +8ABAH= 73 kJExplain the effect of the following on the reaction equilibirum:(1) Removed [A] (2) IT (3) ↑ PC) For a system in which the following reaction occurs: CH4 + H20 CO + 3H2Assume there are present initially 3 mole CH, 1 mol H20, 2mol CO and 4 mol H2.Determine expreession for the mol fraction yi as afunction of (H20 and H2)?

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Q2/ A The following reaction was monitored as a function of time: A+ B+C A plot of In[A] versus time yields a straight line with slope=-0.0045 s 1) What is the value of the rate constant, k, for this reaction at this temperature? 2) What is the half life? 3) If the initial concentration of A is 0.250 mol.L' what is the concentration of A after 225 s?

Q2/ A The following reaction was monitored as a function of time: A+ B+C A plot of In[A] versus time yields a straight line with slope=-0.0045 s 1) What is the value of the rate constant, k, for this reaction at this temperature? 2) What is the half life? 3) If the initial concentration of A is 0.250 mol.L' what is the concentration of A after 225 s?

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter11: Rate Of Reaction

Section: Chapter Questions

Problem 81QAP: The hypothetical reaction QR+Xproductswas monitored at 27C as a function of time. The following...

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A study of the rate of the reaction represented as 2AB gave the following data: Time (s) 0.0 5.0 10.0 15.0 20.0 25.0 35.0 [A](M) 1.00 0.775 0.625 0.465 0.350 0.205 0.230 (a) Determine the average rate of disappearance of A between 0.0 s and 10.0 s, and between 10.0 s and 20.0 s. (b) Estimate the instantaneous rate of disappearance of A at 15.0 s from a graph of time versus [A]. What are theunits of this rate? (c) Use the rates found in parts (a) and (b) to determine the average rate of formation of B between 0.00 s and 10.0 s, and the instantaneous rate of formation of B at 15.0 s.
Derive expressions for the half-life of zero-, first-, and second-order reactions using the integrated rate law for each order. How does each half-life depend on concentration? If the half- life for a reaction is 20. seconds, what would be the second half-Life assuming the reaction is either zero, first, or second order?
11.41 For a drug to be effective in treating an illness, its levels in the bloodstream must be maintained for a period of time. One way to measure the level of a drug in the body is to measure its rate of appearance in the urine. The rate of excretion of penicillin is first order, with a half-life of about 30 min. If a person receives an injection of 25 mg of penicillin at t = 0, how much penicillin remains in the body after 3 hours?
The hypothetical reaction QR+Xproductswas monitored at 27C as a function of time. The following plots are obtained: (a) Write the rate expression for the reaction. (b) What is the rate constant if the rate of the reaction is 0.29 mol/L min when [ QR ]=[ X ]=1.000M? (c) What is the half-life for the consumption of QR when [ QR ]=0.0866M? (d) If the initial concentration of [ X ]=5.00M, what is [ X ] after 4.7 min?
A substance undergoes first-order decomposition. After 40.0 min at 500°C, only 12.5% of the original sample remains. YYliat is the half-life of the decomposition? If the original sample weighed 243 g, how much would remain after 2.00 h?
Regular ?ights of supersonic aircraft in the stratosphere ale of concern because such aircraft produce nitric oxide, NO, as a byproduct in the exhaust of their engines. Nitric oxide reacts with ozone, and it has been suggested that this could contribute to depletion of the ozone layer. The reaction NO+O3NO2+O2 is first order with respect to both NO and O3 with a rate constant of 2.20107 L/mol/s. What is the instantaneous rate of disappearance of NO when [NO]=3.3106 M and [O3]=5.9107M?
Experiments have shown that the average frequency of chirping by a snowy tree cricket (Oecanthus fultoni) depends on temperature as shown in the table. Chirping Rate (per min) Temperature (C) 178 25.0 126 20.3 100. 17.3 What is the apparent activation energy of the process that controls the chirping? What is the rate of chirping expected at a temperature of 7.5C?
(a) From data in Table 11.1, calculate the rate of reaction for each time interval: (i) from 40.0 s to 60.0 s; (ii) from 20.0 s to 80.0 s; (iii) from 0.0 to 100.0 s. (b) Use all of the data in the first two columns of Table 11.1 to draw a graph with time on the horizontal (x) axis and concentration on the vertical (y) axis. Draw a smooth curve through the data. On the graph, draw lines that correspond to [Cv+]/t for each interval. (c) Why is the rate not the same for each time interval in part (a), even though the average time for each interval is 50.0 s? (That is, for interval i, the average time is (40.0 s + 60.0 s)/2 = 50.0 s.) Write an explanation of the reason for a friend who is taking this course, and ask your friend to evaluate what you have written.
When formic acid is heated, it decomposes to hydrogen and carbon dioxide in a first-order decay. HCOOH(g) CO2(g) + H2(g) At 550 C, the half-life of formic acid is 24.5 minutes. (a) What is the rate constant, and what are its units? (b) How many seconds are needed for formic acid, initially 0.15 M, to decrease to 0.015 M?
The reaction AB+C is known to be zero order in A and to have a rate constant of 5.0 102 mol/L s at 25C. An experiment was run at 25C where [A]0 = 1.0 103 M. a. Write the integrated rate law for this reaction. b. Calculate the half-life for the reaction. c. Calculate the concentration of B after 5.0 103 s has elapsed assuming [B]0 = 0.
11.64 HBr is oxidized in the following reaction: 4 HBr(g) + O2(g) —• 2 H2O(g) + 2 Br,(g) A proposed mechanism is HBr + O2 -* HOOBr (slow) HOOBr + HBr — 2 HOBr (fast) HOBr + HBr — H2O + Bn (fast) Show that this mechanism can account for the correct stoichiometry. Identify all intermediates in this mechanism. What is the molecularity of each elementary’ step? Write the rate expression for each elementary' step. Identify the rate-determining step.