Question 29 Suppose that a distribution constant for an amine, B, is Kp = 4.50 and the acid dissociation constant of BH* is Ka=1.90 x 109. If 5.00x10¹ L of 5.10x101 M aqueous amine is extracted with 1.50x101 L of solvent, what will be the formal concentration remaining in the aqueous phase a) at pH 10.50? and b) at pH 4.00?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter14: Acids And Bases
Section14.9: Lewis Acids And Bases
Problem 14.26E
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Question 29
Suppose that a distribution constant for an amine, B, is Kp = 4.50 and the acid dissociation
constant of BH* is Ka=1.90 x 109. If 5.00x10¹ L of 5.10x101 M aqueous amine is extracted with
1.50x101 L of solvent, what will be the formal concentration remaining in the aqueous phase
a) at pH 10.50?
and
b) at pH 4.00?
Transcribed Image Text:Question 29 Suppose that a distribution constant for an amine, B, is Kp = 4.50 and the acid dissociation constant of BH* is Ka=1.90 x 109. If 5.00x10¹ L of 5.10x101 M aqueous amine is extracted with 1.50x101 L of solvent, what will be the formal concentration remaining in the aqueous phase a) at pH 10.50? and b) at pH 4.00?
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