Question b) calculate deltaH for the overall reaction using the following data for the indicated bond dissociation energies:

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter10: Organohalides
Section10.2: Preparing Alkyl Halides From Alkanes: Radical Halogenation
Problem 4P: Taking the relative reactivities of 1°, 2°, and 3° hydrogen atoms into account, what product(s)...
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Question b) calculate deltaH for the overall reaction using the following data for the indicated bond dissociation energies:
1-'Brom
añe or
Lhe prouutts.
그
2
CH3CH2CHACHAB t HBr
CH 3CHCH2CH3
2-bromo buutane
Br
H-Br
b) Calculate AH° for the overall reaction using the following data for the indicated bond dissociation
energies:
CH, CH,-CH - CH,
AH° = 100 kcal/mol
H
CH, CH, CH, CH2
AH° = 105 kcal/mol
Br-Br AH° = 46 kcal/mol
CH, CH;-CH - CH,
AH° = 70 kcal/mol
Br
CH3CH2CH2어2
12 AH° = 74 kcal/mol
Br
H-Br AH° = 87.5 kcal/mol
c) Propose a step-by-step mechanism for the major product only.
2:Bro initiation Step
hv
Transcribed Image Text:1-'Brom añe or Lhe prouutts. 그 2 CH3CH2CHACHAB t HBr CH 3CHCH2CH3 2-bromo buutane Br H-Br b) Calculate AH° for the overall reaction using the following data for the indicated bond dissociation energies: CH, CH,-CH - CH, AH° = 100 kcal/mol H CH, CH, CH, CH2 AH° = 105 kcal/mol Br-Br AH° = 46 kcal/mol CH, CH;-CH - CH, AH° = 70 kcal/mol Br CH3CH2CH2어2 12 AH° = 74 kcal/mol Br H-Br AH° = 87.5 kcal/mol c) Propose a step-by-step mechanism for the major product only. 2:Bro initiation Step hv
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