* Question Completion Status! Shown below is a calibration curve for the analysis of theobromine and caffeine in chocholate. if an unknown sample has a caffiene peak height of 3.50 cm what is the concentration of caffeine in the sample in ppm? 20 Peak height (centimeters) 0 0 Theobromine y = 0.1977x-0.2104 Unknown 25 Figure 0-7 Quantate Chemical Analysis Seventh Edition 2007 Freeman and Company Caffeine y=0.088 4x-0.030 3 75 Analyte concentration (parts per million) 50 100 Feb 2 8
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- An unknown sample of Cu2+gave an absorbance of 0.262. Then 1.00 mL of solution containing 100 ppm (ug/mL)Cu2+was mixed with 95.0 mL of the unknown and the mixture was diluted to 100 mL in a volumetric flask with deionized water. The absorbanceof the new solution was 0.500. a.Denoting the initial unknown concentrationas [Cu2+]i,write an expression for the final concentrationafter dilution [Cu2+] b.Find [Cu2+]in the unknown.SCE students measured the concentration of HCl in a solution by titrating with different indicators to find the end point.Indicator Mean HCl concentration (M)(± standard deviation)Number of measurementsBromothymol blue 0.09565 ± 0.00225 28Methyl red 0.08686 ± 0.00098 18Bromocresol green 0.08641 ± 0.00113 29Is the difference between indicators 1 and 2 significant at the 95% confidence level? Answer the same question for indicators 2 and 3Rinse and fill the buret with 0.100 M HCl solution. Transfer accurately 25.0 mL of saturated calcium hydroxide solution (2g of calcium hydroxide per 100 ml of water) into two separate E-flasks. Add 2 drops of phenolphthalein to each flask and titrate each solution until the pink color disappears. Voume of HCl used: Trial 1= 6.80ml; Trial 2 = 6.30mL Determination of solubility and Ksp of calcium hydroxide 2. Compute for the moles of H+ used and the moles of OH- present. moles of H+ used = (concentration of HCl) × (volume of HCl used)moles of OH- = moles of H+ used 3. Construct an ICE table for the reaction.4. Calculate the molar solubility (in mol/L) of OH- and Ca2+.5. Determine the solubility of Ca(OH)2 in g/L. (MM of Ca(OH)2 = 74.096 g/mol)6. Calculate the Ksp of Ca(OH)2.7. Compute for the percent error of the experimental value for Ksp of Ca(OH)2 with the literature value.(Ksp of Ca(OH)2 = 8.0 × 10-6 at 25°C)
- 25 ml of pickled brine was taken from an apple pickled with vinegar and diluted to 500 ml, 25 ml of this was taken and acidity was determined with 0.2 N (Factor: 1.05) NaOH. In the main trials, 6.3 ml - 6.5 ml - 6.9 ml, respectively, 0.1 ml base was used in the analysis without using the sample.For example, how many ppm is its acidity?From a 10-mL sample, a 1-mL aliquot was taken and diluted to 100mL. From this, a 5-mL aliquot was taken and diluted to 20mL.The final 20mL was found to have a concentration of 0.004M analyte X.What is the concentration of analyte X in the 10-mL sample?An analysis of city drinking water for total hardness was done by two students in the laboratory and produced the following results (in ppm CaCO3): Student A: 228.3, 226.4, 226.9, 227.1, and 228.6. Student B: 229.5, 226.1, 230.7, 223.8, and 227.5 what is the coefficient variation?
- Procedure Preparation of Dilute Solution of Vinegar • Using a 10 mL pipette, transfer 10mL of vinegar into 100 mL volumetric flask. • Dilute to mark of the volumetric flask using distilled water. B. Titration of Diluted Solution of Vinegar • Transfer 25 mL of diluted solution to 250 mL Erlenmeyer flask. • Add 0.5 mL phenolphthalein indicator. Set aside. • Transfer 50mL of 0.110 M NaOH into a 50 mL burette. • Titrate the diluted solution until the phenolphthalein endpoint (very faint pink). • Record volume of NaOH used. Answer the question: What is the experimentally determined concentration of acetic acid in your vinegar solution: (Please give your answer to three significant figures.) ______ M Acetic AcidAn analysis of city drinking water for total hardness was done by two students in the laboratory and produced the following results (in ppm CaCO3): Student A: 228.3, 226.4, 226.9, 227.1, and 228.6. Student B: 229.5, 226.1, 230.7, 223.8, and 227.5 a. What is the mean?How many grams of NaAsO, should be weighed out to prepare a stock solution of 100 mg/L in 500 mL deionized water. Use the stock solution to prepare 4 different standard solution that can be used to prepare an analytical calibration curve to measure the concentration of 750 sample in the concentration range of 10-35 mg/L. Draw a proposed calibration curve (based on the results you achieved).
- In which of the following mixture(s) would CaF2(s) (Ksp = 4.0 x 10-11) form? 30 mL of 0.00020 M Ca(NO3)2 + 20 mL of 0.00125 M NaF 20 mL of 0.00020 M Ca(NO3)2 + 30 mL of 0.00125 M NaF 10 mL of 0.00020 M Ca(NO3)2 + 40 mL of 0.00125 M NaF Group of answer choices I only II only I and II I and IIIIndicate the appropriate protocol below to prepare the required solution. a) Solution 5 Preparation: Prepare: 10 mL of 23% mannitol From: solid mannitol Procedure: b) Solution 2 Preparation: Prepare: 0.5 liters of 0.01 mg/mL ascorbic acid From: solid ascorbic acid , MW = 176.1 g/mol Procedure: C) Solution 3 Preparation: Prepare: 1 liter of 150 mM Tris From: 1 Molar Tris stock solution Procedure:Method used was Volhard Method Sample preparation: 5ml sample diluted in 100 ml. 20ml aliquot was used for analysis. Concentration of AgNO3: 0.0609M Calculate mass of NaCl and % NaCl (w/v)