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- Give only typing answer with explanation and conclusion Consider the compounds below. First, identify if the compound is covalent or ionic. If covalent, identify the intermolecular forces that compound will have. Then, rank them based on their melting point – with 1 being highest, 5 being lowest. NaBr LiF H2S C2H6 H2OBromine ( Br₂ ) is a liquid at room temperature . What is the attractive force that exists among Br2 molecules in the liquid ?3) In order to determine electronic geometry of molecules, valence shell electron-pair repulsion theory is utilized, what is the acronym for this theory: 4) Write the following lower case Greek letters: lambda: and nu: 5) Using Dimensional Analysis show all work to calculate the mass of a solution prepared from 100 mL DI water (density = 1.00 g/mL) and 5 g NaCl (s).
- 12.A compound is a pure substance whose smallest representative is identified as:a)Molecule b)Atom c)Ion d)Chemical species e)Atomic orbitalAnswer each question and justify your answer by doing ALL of the following: • Identify the type of substance and important interparticle force(s) for both substances. − Explain how you know (substances and forces). − For each molecular substance, fully justify how you know if it is polar or nonpolar. Provide a Lewis structure, a geometry sketch, calculation of |ΔEN| values, and a discussion of symmetry. • Identify which of the two substances has stronger interparticle forces. If they have the same type of interparticle force, explain how you know which is stronger. • Answer the question by connecting the property asked about to strength of interparticle forces. • Use complete sentences, write all words out (no abbreviations) and be specific and complete with all explanations. Do not refer to any actual data. 10-3. Does CH4O or CH3F have the higher boiling point? 10-5. Does BaSO4 or KCN have the lower melting point?1) Using principles of chemical bonding and/or intermolecular forces, explain each of the following. (a) Xenon has a higher boiling point than neon has. (b) Solid copper is an excellent conductor of electricity, but solid copper chloride is not. (c) SiO2 melts at a very high temperature, while CO2 is a gas at room temperature, even though Si and C are in the same chemical family. (d) Molecules of NF3 are polar, but those of BF3 are not. 2) Using principles of chemical bonding and/or intermolecular forces, explain each of the following: (a) MgCl2 and SiCl4 (b) MgCl2 and MgF2 (c) F2 and Br2 (d) F2 and N2 Note: Please Briefly Explain
- 1. Which of the following would you expect to have the higher melting point? Explain why.Both NH3, NCl3, and NF3 are all polar. Here is a data table with some additional information: Name Melting Point (°C) Boiling Point (°C) Molecular Geometry Nitrogen trihydride (ammonia) -77.7 -33.3 Trigonal Pyramidal Nitrogen trichloride -40.0 71.0 Trigonal Pyramidal Nitrogen trifluoride -207 -129 Trigonal Pyramidal Considering intermolecular forces, for what reason would nitrogen trichloride have such a high boiling point? choose one: 1.The molecular geometry makes it the most polar of the compounds 2.The larger mass and larger electron cloud means stronger LDF 3.It can participate in H-bonding 4.Unlike the other substances, it is polar. 5.The small mass means it takes less energy to break the IMFA portion of a two-dimensional “slab” of NaCl(s) is shownhere (see Figure 8.2) in which the ions are numbered.(a) Which colored balls must represent sodium ions?(b) Which colored balls must represent chloride ions?(c) Consider ion 5. How many attractive electrostatic interactionsare shown for it? (d) Consider ion 5. How manyrepulsive interactions are shown for it? (e) Is the sum of the attractiveinteractions in part (c) larger or smaller than the sumof the repulsive interactions in part (d)? (f) If this pattern ofions was extended indefinitely in two dimensions, would thelattice energy be positive or negative? [Section 8.2]
- Suppose a chloride ion and a sodium ion are separated by a center–centerdistance of 5 Å. Is the interaction energy (the energy required to pull theminfinitely far apart) predicted to be larger if the medium between them iswater, or if it is n-pentane? (as shown)If Ca2+, Na+, and F- each have ionic radii ~1.16. Which ionic bond is stronger: Ca-F or Na-F?If Ca2+ is often bound on the surface of a protein by carboxylic acid functional groups. If the pKa of a particular -COOH group is 4.2, wouldyou predict Ca2+ to be most tightly bound at pH 8, pH 4.2, or pH 3? Explain your answer.Which of the following statements is/are correct? l. Water is good at dissolving ions and polar molecules, but poor at dissolving nonpolar molecules. ll. A polar molecule is one that is uncharged, but has an asymmetric internal distribution of charge, leading to partially positive and partially negative regions. lll. Water interacts differently with charged and polar substances than with nonpolar substances because of the polarity of its own molecules. lV. Water molecules are polar, with partial positive charges on the hydrogen, a partial, and negative charge on the oxygen.Mixing SbCl3 and GaCl3 in a 1;1 molar ratio (usingliquid sulfur dioxide as a solvent) gives a solid ioniccompound of empirical formula GaSbCl6. A controversyarises over whether this compound is ( ) SbCl2 + ( ) GaCl 4 - or( ) GaCl+ 2 ( ) SbCl 4 -(a) Predict the molecular structures of the two anions.(b) It is learned that the cation in the compound has abent structure. Based on this fact, which formulationis more likely to be correct?