Rate Determination and Activation Energy   1. Plot a graph of your data above, using Temperature (°C) as the x-axis, and the rate constant, k, as the y-axis. 2. Determine the activation energy, Ea, by plotting the natural log of k vs. the reciprocal of absolute temperature. You can calculate 1/T (first convert T to K) and ln k manually, or use Excel to do it. You will also need to make a graph. 3. Calculate the activation energy, Ea, for the reaction. To do this, first, calculate the best fit line equation for the data in Step 2. Use the slope, m, of the linear fit to calculate the activation

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
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Chapter11: Chemical Kinetics
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Problem 11.110PAE: When formic acid is heated, it decomposes to hydrogen and carbon dioxide in a first-order decay:...
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Rate Determination and Activation Energy

 

1. Plot a graph of your data above, using Temperature (°C) as the x-axis, and the rate constant, k, as the y-axis.

2. Determine the activation energy, Ea, by plotting the natural log of k vs. the reciprocal of absolute temperature. You can calculate 1/T (first convert T to K) and ln k manually, or use Excel to do it. You will also need to make a graph.

3. Calculate the activation energy, Ea, for the reaction. To do this, first, calculate the best fit line equation for the data in Step 2. Use the slope, m, of the linear fit to calculate the activation

4. A well-known approximation in chemistry states that the rate of a reaction often doubles for every 10°C increase in temperature. Use your data to test this rule. (Note: It is not necessarily equal to 2.00; this is just an approximate value and depends on the activation energy for the reaction.) Choose the data that is closest to 10°C apart and check if the rule holds.

5. Using the rate constant and precise temperature value for the trial that was done at room temperature (~20°C), as well as the Ea value you obtained in Step 3 above, calculate the value of the rate constant at 40°C.

 

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