Reaction of p-bromobenzoic acid with KOH produces which of the following products? A) potassium p-bromobenzoate B) p-bromobenzaldehyde C) p-bromobenzene D) p-bromophenol E) p-bromophenyl potassium
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- The trimethylsilyl (TMS) protecting group is one of several silicon protecting groups for alcohols. For each reaction, draw the mechanism for the protection of (R)-3-bromo-1-butanol with the following silyl chlorides, using triethylamine as the base: (a) terf-butyldimethylsilyl chloride (TBS-C1] (b) triisopropylsilyl chloride (TEPS-C1) (c) triethylsilyl chloride (TES-C1)Show the products from reaction of p-bromoaniline with the following reagents: (a) CH3I (excess) (b) HCl (c) HNO2, H2SO4 (d) CH3COCl (e) CH3MgBr (f) CH3CH2Cl, AlCl3 (g) Product of (c) with CuCl, HCl (h) Product of (d) with CH3CH2Cl, AlCl3Which of the following starting materials and reagents would be best to produce a racemic mixture of 3-methyl-3-hexanol? a. heptanone and 1. CH3MgBr 2. H3O+ b. hexanal and 1. CH3MgBr, 2. H3O+ c. 3-hexanone and 1. CH3MgBr, 2. H3O+ d. butanal and 1. CH3CH2MgBr, 2. H3O+
- What is the major product(s) of each of the following reactions? a. bromination of p-methylbenzoic acid b. chlorination of o-benzenedicarboxylic acid c. bromination of p-chlorobenzoic acid d. nitration of p-fluoroanisole e. nitration of p-methoxybenzaldehyde f. nitration of p-tert-butylmethylbenzeneThe product of the following reactions will be ________ . 1) Benzene + + 1/2 I2 + HNO3 2) Formyl chloride (acyl chloride of formic acid-HCO2H) and AlCl3 4-iodobenzoic acid 3-iodobenzaldehyde 2-iodobenzaldehyde benzoic acid 3-iodobenzylalcoholgas, Cl¬CH2CH2¬S¬CH2CH2¬Cl, was used as a poisonous chemical agentin World War I. Mustard gas is much more toxic than a typical primary alkyl chloride. Itstoxicity stems from its ability to alkylate amino groups on important metabolic enzymes,rendering the enzymes inactive.(a) Propose a mechanism to explain why mustard gas is an exceptionally potent alkylatingagent.(b) Bleach (sodium hypochlorite, NaOCl, a strong oxidizing agent) neutralizes and inactivates mustard gas. Bleach is also effective on organic stains because it oxidizes coloredcompounds to colorless compounds. Propose products that might be formed by thereaction of mustard gas with bleach.
- Mustard gas, Cl¬CH2CH2¬S¬CH2CH2¬Cl, was used as a poisonous chemical agentin World War I. Mustard gas is much more toxic than a typical primary alkyl chloride. Itstoxicity stems from its ability to alkylate amino groups on important metabolic enzymes,rendering the enzymes inactive.(a) Propose a mechanism to explain why mustard gas is an exceptionally potent alkylatingagentDraw the product(s) of each of the following reactions: a. benzoic acid + HNO3/H2SO4 b. isopropylbenzene + Cl2 + FeCl3 c. p-xylene + acetyl chloride + AlCl3 followed by H2O d. o-methylaniline + benzenediazonium chloride e. cyclohexyl phenyl ether + Br2 f. phenol + H2SO4 + ∆ g. ethylbenzene + Br2/FeBr3 h. m-xylene + Na2Cr2O7 + HCl + ∆Which of the following reactions provides iso-propyl methyl ether in a high yield? A) potassium iso-propoxide + iodomethane B) sodium methoxide + iso-propyl bromide C) methanol + iso-propyl alcohol in the presence of KOH D) iodomethane + iso-propyl bromide in the presence of KOH
- Which reagents are best used to produce 4-methyl-2-pentanol from a ketone? a. amins and trace acid, followed separetely H2/PD/C b. sodium cyanide followed by HCl c. sodium borohydridd followed by acidic work up d. hydrogen cyanide followed by HCl e. none of the aboveIn electrophilic aromatic substitution reactions a Iodine substituent on the aromatic ring is: a) An activator and a m-director. b) A deactivator and an o,p-director. c) A deactivator and an o,p-director. d) A deactivator and a m-director e) Iodine cannot bond with benzene.Chemistry Draw the product formed when phenylacetaldehyde (C6H5CH2CHO) is treated with reach reagent: f. (CH3)2CHNH2, mild acid g. (CH3CH2)2NH, mild acid h. CH3CH2OH (excess), H+ i. piperidine, mild acid j. HOCH2CH2OH, H+