Reaction of the cyclic product with a nitron (see below) yields a mixture of heterocyclic Diastereomers. ND +. NO, ) Name the reaction g) Draw one of the diastereomers. h) Show the orbital interaction and explain all aspects of stereoselectivity for the diastereomer that you selected.

Reaction of the cyclic product with a nitron (see below) yields a mixture of heterocyclic Diastereomers. ND +. NO, ) Name the reaction g) Draw one of the diastereomers. h) Show the orbital interaction and explain all aspects of stereoselectivity for the diastereomer that you selected.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter10: Organohalides

Section10.SE: Something Extra

Problem 18MP: Draw the electron-pushing mechanism for the propagation steps of the allylic bromination reactions...

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

Reaction of the cyclic product with a nitron (see below) yields a mixture of heterocyclic
Diastereomers.
ND
+.
NO,
) Name the reaction
g) Draw one of the diastereomers.
h) Show the orbital interaction and explain all aspects of stereoselectivity for the
diastereomer that you selected.

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