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[ReferencEIJ How many monochloro substitution products are produced when the alkane below is chlorinated? Consider both constitutional isomers and stereoisomers. The number of monochloro substitution products is

[ReferencEIJ How many monochloro substitution products are produced when the alkane below is chlorinated? Consider both constitutional isomers and stereoisomers. The number of monochloro substitution products is

Organic Chemistry
Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter3: Organic Compounds: Alkanes And Their Stereochemistry
Section3.SE: Something Extra
Problem 54AP: In the next chapter we'll look at cycloalkanes—saturated cyclic hydrocarbons—and we’ll see...
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[Reference How many monochloro substitution products are produced when the alkane below is chlorinated? Consider both constitutional isomers and stereoisomers. x The number of monochloro substitution products is
Transcribed Image Text:[Reference How many monochloro substitution products are produced when the alkane below is chlorinated? Consider both constitutional isomers and stereoisomers. x The number of monochloro substitution products is
In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H bonds react at relative rates of 1 : 3.9 : 5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B, the A:B product ratio will be 2. Consider chlorination of the alkane below at 35 °C. a C 1. Specify the most reactive C-H bond(s), a-c. Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. a,c
Transcribed Image Text:In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H bonds react at relative rates of 1 : 3.9 : 5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B, the A:B product ratio will be 2. Consider chlorination of the alkane below at 35 °C. a C 1. Specify the most reactive C-H bond(s), a-c. Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, i.e. a,c. 2. Specify the site of chlorination in the major monochloro substitution product, a-c. Two products that form in comparable quantities should be separated by commas, i.e. a,c
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