The maximum kinetic isotope effects (KIE) are exhibited for the reactions of molecules which involve the isotopes of hydrogen. By outlining the origins of KIE, explain why this is so. a. (i) (ii) Present an expression which gives the dependence of the rate constant k on H/D isotopic substitution i.e., predict kH/ kp.

The maximum kinetic isotope effects (KIE) are exhibited for the reactions of molecules which involve the isotopes of hydrogen. By outlining the origins of KIE, explain why this is so. a. (i) (ii) Present an expression which gives the dependence of the rate constant k on H/D isotopic substitution i.e., predict kH/ kp.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter34: Miscellaneous Separation Methods

Section: Chapter Questions

Problem 34.19QAP

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