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s-p Mixed Orbital Wavefunctions: more 2p, than 2s more 2s than 2p, Answer: Example: The lo, orbital of B2 is more stabilized than expected for a pure 2s + 2s interaction a) The lo orbital of B2 is less destabilized than expected for a pure 2s – 2s interaction b) The 20, orbital of B2 is more destabilized than expected for a pure 2p, – 2pz interaction c) The 20, orbital of B2 is more destabilized than expected for a pure 2p, + 2pz interaction

s-p Mixed Orbital Wavefunctions: more 2p, than 2s more 2s than 2p, Answer: Example: The lo, orbital of B2 is more stabilized than expected for a pure 2s + 2s interaction a) The lo orbital of B2 is less destabilized than expected for a pure 2s – 2s interaction b) The 20, orbital of B2 is more destabilized than expected for a pure 2p, – 2pz interaction c) The 20, orbital of B2 is more destabilized than expected for a pure 2p, + 2pz interaction

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 71AP: The MO of the ground state of a heteronuclear diatomicmoleculeAB is mol=CAA+CBB If a bonding...
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s-p Mixed Orbital Wavefunctions: more 2p, than 2s more 2s than 2pz Answer: Example: The lơ, orbital of B2 is more stabilized than expected for a pure 2s + 2s interaction a) The lo orbital of B2 is less destabilized than expected for a pure 2s – 2s interaction b) The 20, orbital of B2 is more destabilized than expected for a pure 2p, – 2p, interaction c) The 20, orbital of B2 is more destabilized than expected for a pure 2p, + 2p, interaction
Transcribed Image Text:s-p Mixed Orbital Wavefunctions: more 2p, than 2s more 2s than 2pz Answer: Example: The lơ, orbital of B2 is more stabilized than expected for a pure 2s + 2s interaction a) The lo orbital of B2 is less destabilized than expected for a pure 2s – 2s interaction b) The 20, orbital of B2 is more destabilized than expected for a pure 2p, – 2p, interaction c) The 20, orbital of B2 is more destabilized than expected for a pure 2p, + 2p, interaction
4) some elements effects the MO ordering for homonuclear diatomics. Using the hybridized s-p orbital wavefunctions below, draw MOs representing each case. An example is given to show you how to answer. we talked about how the energy proximity of the 2s and 2p orbitals for
Transcribed Image Text:4) some elements effects the MO ordering for homonuclear diatomics. Using the hybridized s-p orbital wavefunctions below, draw MOs representing each case. An example is given to show you how to answer. we talked about how the energy proximity of the 2s and 2p orbitals for
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