S.10. Describe the product formed as a result of the reaction between cyclohexanone and 3-butene-2-one by also writing the mechanism of the reaction. 1'CH,ON H;C, 2 HO CH,
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- What organic product would you obtain from reaction of 1-pentanol with CrO3, H2O, H2SO4?A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactionsDisiamylborane adds only once to alkynes by virtue of its two bulky secondary isoamylgroups. Disiamylborane is prepared by the reaction of BH3 # THF with an alkene.(a) Draw the structural formulas of the reagents and the products in the preparation ofdisiamylborane.(b) Explain why the reaction in part (a) goes only as far as the dialkylborane. Why isSia3B not formed?
- Predict the major products formed when 2- methyl-1-butene reacts with: H2, Pt/25°C. Show the reaction mechanism the given alkene reactionsProvide the E2 mechanism for β-elimination reactionemploying 2-chloro-2-methylbutane to prepare 2-methyl-2-butene and 2-methyl-1-butene reaction. Use the actual structures of thereactants and products. Explain which of the alkenes is the major product ofthis reaction ?Predict the organic products of the reaction of 2 butene with each reagent. Be sure to indicate stereochemistry and regioselectivity where appropriate. a. Br2 in H2O b. Hg(OAc)2, H2O c. Product from (b) + NaBH4
- When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.Compounds A, B, and C have the same molecular formula C4H8. They all react wotu H2/PtO2 to give the same compound. The reaction of A or B with H2O/H2SO4 or with BH3-THF, followed by treatment with a basic solution of hydrogen peroxide, gives the same compound, namely D. The reaction of C with H2O/H2SO4 also gives D. However, the reaction of C with BH3-THF, followed by HO-, H2O2 gives a new compound, E. Provide the identity of A, B, C, D, and E along with explanations of reactivity.What is the reaction when trans-2-butene reacts with 1.KMnO4/-OH in cold 2. hotKMnO4/-OH 3.HBr in the presence of peroxide
- 2-methyl-1-propanol heated with acidic K2Cr2O7 reactionWrite equations for the reaction of 1-butanol with reagent. Where you predict no reaction, write NR. Q) K2Cr2O7, H2SO4, H2O, heatWhat will be the major product obtained from the reaction of Br2 with 1-butene if the reaction is carriedout ina. dichloromethane? b. water? c. ethyl alcohol? d. methyl alcohol?