Saccharide X occurs in the roots of several species of plants. Deduce the structure of saccharide x from the following data: . Acidic hydrolysis of 1 mol of stachyose yields 2 mol of D-galactose, 1 mol of D-glucose, and 1 mol of D-fructose. E. Stachyose is a nonreducing sugar. . Treating stachyose with an a-galactosidase produces a mixture containing p-galactose, sucrose, and a nonreducing trisaccharide called maffinose. . Acidic hydrolysis of raffinose gives D-glucose, D-fructose, and D-galactose. Treating raffinose with an a-galactosidase yields D-galactose nd sucrose. Treating raffinose with invertase (an enzyme that hydrolyzes sucrose) yields fructose and melibiose . Methylation of saccharide x followed by hydrolysis yields 2,3,4,6-tetra-O-methyl-D-galactose, 2,3,4-tri-O-methyl-D-galactose, „3,4-tri-O-methyl-D-glucose, and 1,3,4,6-tetra-O-methyl-D-fructose.

Biochemistry
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Author:Mary K. Campbell, Shawn O. Farrell, Owen M. McDougal
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Chapter3: Amino Acids And Peptides
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Problem 13RE: MATHEMATICAL An organic chemist is generally happy with 95% yields. If you synthesized a polypeptide...
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Draw the structure.
Saccharide X occurs in the roots of several species of plants. Deduce the structure of saccharide x from the following data:
1. Acidic hydrolysis of 1 mol of stachyose yields 2 mol of D-galactose, 1 mol of D-glucose, and 1 mol of D-fructose.
2. Stachyose is a nonreducing sugar.
3. Treating stachyose with an a-galactosidase produces a mixture containing D-galactose, sucrose, and a nonreducing trisaccharide called
raffinose.
4. Acidic hydrolysis of raffinose gives D-glucose, D-fructose, and D-galactose. Treating raffinose with an a-galactosidase yields D-galactose
and sucrose. Treating raffinose with invertase (an enzyme that hydrolyzes sucrose) yields fructose and melibiose
5. Methylation of saccharide x followed by hydrolysis yields 2,3,4,6-tetra-O-methyl-D-galactose, 2,3,4-tri-0-methyl-D-galactose,
2,3,4-tri-O-methyl-D-glucose, and 1,3,4,6-tetra-O-methyl-D-fructose.
Transcribed Image Text:Draw the structure. Saccharide X occurs in the roots of several species of plants. Deduce the structure of saccharide x from the following data: 1. Acidic hydrolysis of 1 mol of stachyose yields 2 mol of D-galactose, 1 mol of D-glucose, and 1 mol of D-fructose. 2. Stachyose is a nonreducing sugar. 3. Treating stachyose with an a-galactosidase produces a mixture containing D-galactose, sucrose, and a nonreducing trisaccharide called raffinose. 4. Acidic hydrolysis of raffinose gives D-glucose, D-fructose, and D-galactose. Treating raffinose with an a-galactosidase yields D-galactose and sucrose. Treating raffinose with invertase (an enzyme that hydrolyzes sucrose) yields fructose and melibiose 5. Methylation of saccharide x followed by hydrolysis yields 2,3,4,6-tetra-O-methyl-D-galactose, 2,3,4-tri-0-methyl-D-galactose, 2,3,4-tri-O-methyl-D-glucose, and 1,3,4,6-tetra-O-methyl-D-fructose.
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