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- Draw the products formed when CH3COCH2CH2CH = CH2 is treated with each reagent:(a) LiAlH4, then H2O;(b) NaBH4 in CH3OH;(c) H2 (1 equiv), Pd-C;(d) H2 (excess), Pd-C;(e) NaBH4 (excess) in CH3OH;(f) NaBD4 in CH3OH.Lithocholic acid is an A–B cis steroid found in human bile. Draw lithocholic acid showing chair conformations, as in Figure 27-11, and tell whether the hydroxyl group at C3 is axial or equatorial.Treatment of -D-glucose with methanol in the presence of an acid catalyst converts it into a mixture of two compounds called methyl glucosides (Section 25.3A). In these representations, the six-membered rings are drawn as planar hexagons. (a) Propose a mechanism for this conversion and account for the fact that only the OH on carbon 1 is transformed into an OCH3 group. (b) Draw the more stable chair conformation for each product. (c) Which of the two products has the chair conformation of greater stability? Explain.
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent.a. HClb. CH3COClc. (CH3CO)2Od. excess CH3Ie. (CH3)2C = Of. CH3COCl, AlCl3g. CH3CO2Hh. NaNO2, HCli. Part (b), then CH3COCl, AlCl3j. CH3CHO, NaBH3CNDraw the products formed (including stereoisomers) when attached compound is reduced with NaBH4 in CH3OH.Draw the products formed when each alkene is treated with BH3 followed by H2O2,HO−. Include the stereochemistry at all stereogenic centers.
- Draw the products formed when (CH3)2C=CH2 is treated with following reagent. [1] BH3; [2] H2O2, HO−When attached halohydrin is treated with NaH, a product of molecularformula C4H8O is formed. Draw the structure of the product and indicateits stereochemistry.What is the major stereoisomer formed when attached alkyl halide is treatedwith KOC(CH3)3?