[ Select ] unpaired d electrons present in the [Rh(NH3)4CI2]* There are a complex, which is a low spin complex. The complex would be [Select] magnet.

Q: Rhol(PPhs)s 9volume eICCtronsinRn in Cr which are The L-type ligands? Oxidanon State of Rn,cr…

A: The L type ligands in [RhCl(PPh3)3] is PPh3; i.e. triphenylphosphine. The L type ligand in Cr(CO)6…

Q: 7) If you were to use a ligand L that was a stronger field ligand than NH3, what color would you…

A: Step : 1             The required answer is follows as :

Q: You have a neutral, 4-coordinate macrocyclic ligand that binds to Ni(II). When a weakly-coordinating…

A: Square-planar Ni(II) complexes are diamagnetic and their colour is usually red, yellow or…

Q: 13. A complex ion has been observed which starts with a violet color with six aqua ligands attached.…

A:

Q: Which ligand below gives the LEAST stability to Pd2+ in forming a square planar complex? О а. NH3 O…

A: a) NH3 will form the least stable complex.  Because we know that more is the basicity of lignad more…

Q: Naz[Fe(CN)4(en)] The complex ion of this compound is known to be diamagnetic. Draw the d-orbital…

A:

Q: Association reaction is the only pathway for ligand substitution in a square planar complex because…

A:

Q: Which dn configuration is not capable of giving low-spin and high-spin complexes in an octahedral…

A: According to the crystal field theory the ligand atom acts as point negative change and the metal…

Q: Illustrate the Transition-Metal Complexes?

A: Transition metals are d-block elements. These elements can co-ordinate with negative or neutral…

Q: and eg t2g d. An analogous compound, [Cu(H₂O)6]2+ has a different arrangement of the Draw the…

A: Given that, a metal complex is [Cu(H2O)6]2+. We have to tell the different arrangement of the…

Q: (a) Draw all the possible isomers of [Fe(NH3);Br3] and for each isomer clearly indicate the…

A: a) There are two possible isomers of the given compound, fac and mer. These are shown as below:…

Q: What energy levels are occupied in a complex such ashexacarbonylchromium(0)? Are any electrons…

A: According to the molecular orbital theory, the atomic orbitals combine to form new molecular…

Q: Amongst the two listed in each question, which complex has a faster ligand exchange rate? Give a…

A:

Q: The complex was synthesized with the formula [Co(CO)2(CN)2Br2] The spectre infrared shows two bands…

A: The complex synthesized is: [Co(CO)2(CN)2Br2]

Q: The compound 1,1,1-trifluoroacetylacetone (tfa- is a bidentate ligand: CF,CC H2CCH3 2+ It forms a…

A:

Q: What determine whether a molecule or ion complex is chiral? How would you differentiate between…

A: A chiral is an object that is not identically super-imposable with a mirror image of itself. An…

Q: F3B-NH3

A: Electron deficient molecule tries to gain stability by accepting electrons from bonded or…

Q: The high spin d complex [Cr(H20]z2* is labile but the low spin d' complex ion [Cr(CN)6]+ is inert.…

A:

Q: Na2[Fe(CN)4(en)] The complex ion of this compound is known to be diamagnetic. Draw the d-orbital…

A:

Q: Explain why the complex Fe(en)3]2 is far less prone to ligand substitution reaction than its…

A: Interpretation -  To explain the complex [Fe(en)3]2+  is far less prone to ligand substitution…

Q: what is the maximum number if unpaired d electrons that an octahedral transition mental complex can…

A: The question is based on the concept of coordination chemistry. We have to identify maximum unpaired…

Q: <p>How can you tell whether a complex ion is optically active?

A: The activity of a complex can be found out by observing the structure of the complex and also…

Q: b) Given (Ni(CN).F as a complex ion. Answer the questions below based on Valence Bond Theory. i)…

A: According to Valence bond theory: The valence shell electronic configuration of Ni atom is 3d8 4s2…

Q: [FeL6]* complex (L indicates a monodentate ligand) has a magnetic m approximately 1.73 B.M. a) What…

A: The electronic configuration is given by, [FeL6]3- i.e. Fe 3+: 18(Ar) 4s0 3d5

Q: The complex compound which has the most inert properties is…. A. [PF6]- B. [SF6] C. [SiF6]2- D.…

A: The inert character of complexes of main block element depend on the oxidation state of metal .…

Q: In the following complex compound, there are d-electrons.

A:

Q: Which of the following is the NOT a step for naming coordination complexes? Select only the best…

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Q: 1) a. Draw the compounds [Fe(CO)6]3+ and [Fe(NH3)6]3+ below. b. Which complex above is more likely…

A: CONCEPT: Strong field : In strong field complexes, pairing of d-electrons will take place in t2g…

Q: Mo(PMes)3(C6HS)2

A:

Q: 3+ cation, the energies of the valence d orbitals on When a certain strong-field ligand forms an…

A:

Q: Discuss for reasons as to which of the following properties [Ni (NH3) 6] C12 complex has. O Strong…

A: The answer is given as follows

Q: 2. Two octahedral complex are shown as below. OCH3 H3CO, OCH3 MeO2C CO,Me Al H3CO OCH3 MeO2C cO,Me…

A: We need to find the oxidation state of the central metal atom. Then we can be able to find the spin…

Q: Depict and explain the Crystal field stabilization theory based on the color the below complexes.…

A:

Q: b) The high-spin đ complex (Cr(H:O)J* is labile, but the low-spin d' complex ion [Cr(CN)e]* is…

A:

Q: The effective atomic number of the [Co (en) 3] Cl3 complex is 36, and the complex obeys this rule.…

A: EAN i.e. effective atomic number rule is number of electrons surrounding to Central metal atom in…

Q: (a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: <p>Hexacyanomanganate(III) ion is a low-spin complex. Draw the crystal field splitting diagram…

A: Hexacyanomanganate (III) ion is a low spin complex because of the presence of cyano ligand, a strong…

Q: or the square planar complex(es) (NH3)2PtCl2, which best possibilities? 2, Wh a. Two isomers exist,…

A: Given that (NH3)2PtCl2  is a square planar complex and it does exits in two isomers- Cis and Trans.

Q: When a certain strong-field ligand forms an octahedral complex with Mn* cation, the energies of the…

A: Electronic configuration of Mn = [Ar] 3d5 4s2 Electronic configuration of Mn3+ = [Ar] 3d4  Under…

Q: The octahedral complex ion [MnCl1* has more unpaired spins than the octahedral complex ion…

A: For [MnCl6]4- The oxidation state for Mn is +2. Cl is a very weak field ligand so it will form a…

Q: A classmate says, “A weak-field ligand usually means the complex is high spin.” Is your classmate…

A: solution;- , “A weak-field ligand usually means the complex is high spin.”  classmate to be correct…

Q: Part A How many unpaired electrons are in the d orbitals of an octahedral complex of Ru3+  assuming…

A: In strong field, electrons enter the eg orbitals only when t2g orbitals are completely filled.

Q: b) Consider (Co(CI).F and (Co(NH3)e]* ions. i. Illustrate the energy level splitting diagram for…

A: Since Cl is weak field ligand then the complex shows high spin  And NH3 is strong field ligand shows…

Q: 3- The gap between the higher and lower energy levels is called the crystal-field splitting energy…

A: Strong field ligands cause a greater splitting of the d-orbitals of the central metal atom, than the…

Q: Three complex ions of cobalt(III), [Co(CN),]?-, [Co(NH;),]*, and (CoF, absorb light at wavelengths…

A: The given complex ions are [Co(CN)6]3-, [Co(NH)6]3+ and [CoF6]3- The given wavelengths are  290 nm,…

Q: Early transition metal ions are generally quite Lewis whereas the ligands they coordinate are Lewis…

A: Eartly transition metal ions  are generally quite lewis acids whereas the Ligands they co ordinate…

Q: Determine whether the following complexes are low spin or high spin complex (i) [Co(CN)6]* [CoF6]3-…

A: In low spin 3d metal complexes, the electrons are paired in the lowest energy state before filling…

Q: The three complex ions [Mn(CN),]³-, [Mn(CN),J*¯, and [Mn(CN),]³- have all been synthesized and all…

A: All three complexes has cyanide ligand, CN- which is a strong field ligand , thus all complexes are…

Q: b) Calculate the orbital multiplicity for a Cr3+ assuming it is a free ion (Not complex). c)…

A: Orbital multiplicity of a metal is its total no.of orientations of orbital angular momentum L. which…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.