Selenic acid (H2SEO4) is a powerful oxidizing acid that dissolves not only silver (as does the related acid H2SO4) but gold, through the following reaction:

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter3: Chemical Reactions
Section3.9: Classifying Reactions In Aqueous Solution
Problem 1RC: 1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does...
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5. Selenic acid (H2SEO4) is a powerful oxidizing acid that dissolves not only silver (as
does the related acid H2SO4) but gold, through the following reaction:
2 Au (s) + 6 H2SEO4 (aq) → Au2(SeO4)3 (aq) + 3 H2SEO3 (aq) + 3 H2O (I)
Determine the oxidation numbers of the atoms in this equation. Which species is
oxidized and which is reduced? Hint: the selenate (SeO42-) and selenite (SeO3²-)
polyatomic ions present in the above reaction are analogous to the sulfate and
sulfite ions.
Transcribed Image Text:5. Selenic acid (H2SEO4) is a powerful oxidizing acid that dissolves not only silver (as does the related acid H2SO4) but gold, through the following reaction: 2 Au (s) + 6 H2SEO4 (aq) → Au2(SeO4)3 (aq) + 3 H2SEO3 (aq) + 3 H2O (I) Determine the oxidation numbers of the atoms in this equation. Which species is oxidized and which is reduced? Hint: the selenate (SeO42-) and selenite (SeO3²-) polyatomic ions present in the above reaction are analogous to the sulfate and sulfite ions.
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