Show how you would prepare the following amide starting with bromocyclohexene and any other reagents. Br a-04 Propose a mechanism for the following transformation when an ethyl magnesium bromide in excess was reacted with the acid chloride followed by heating with concentrated sulfuric acid. x

Show how you would prepare the following amide starting with bromocyclohexene and any other reagents. Br a-04 Propose a mechanism for the following transformation when an ethyl magnesium bromide in excess was reacted with the acid chloride followed by heating with concentrated sulfuric acid. x

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.6: Synthesis Of Amines

Problem 13P

See similar textbooks

Related questions

Q: Predict the result (miscible/immiscible) for mixing the following with water: a) 1-pentanol…

A: Miscible compounds are those which can dissolve completely into each other without giving any…

Q: 1. Calculate the heat of combustion (kJ) of propane, C3H, using the listed standard enthalpy of…

Q: Hz C. CH₂ ・CH-CH=CH₂ Br₂/cala (Bromination) Вр CH₂₂ CH 4-o H₂C - CH 1 Br Dehalogenation CH CE CH -…

Q: Match the following pair of organic compounds with the specific type of isomerism that they exhibit…

A: Isomers are the molecules that have same molecular formula but differ in their structure.

Q: i. NaH, DMF ii. CH3CH₂Br iii. NaOH, H₂O iv. H₂O*, heat ?

Q: The burning of limestone goes only 50 % to completion in a certain kiln. What is the mass…

A: Given: reaction goes to 50% completion To find: What is the mass composition of the solid withdrawn…

Q: need chemoselectivity. Under this 1. The relative reactivity of two different functional groups,…

Q: 30 Br he 31 + HO. لماذا و( 32 OH 33; phenol e Br 34

Q: a or b could be tried first. O₂N CI stacal 3 nitration ces موجود OEt para is major OEt 0₂N C-C…

A: Aromatic Reactions

Q: Magnesium and Hydrochloric acid react according to the reaction:…

Q: Determine the oxidation number for the indicated atom in each presented formula. 1. What is the…

A: “Since you have posted a question with multiple sub-parts, we will solve first three sub-parts for…

Q: Enhanced oil recovery (EOR) is used in refinery operations by flooding a bed of rocks with a…

A: determination of freezing point of solution

Q: 14. The reaction CO₂(g) + C(s) = 2 CO(g) has Kp=5.78 at 1200 K. Calculate the total pressure at…

Q: Which one of the following is correct for the sparingly soluble salts? 1. The cation plus its…

A: To choose the correct answer

Q: How to properly use significant figures in this case? Ccal = (-ΔHrxn x nLR)/ΔT Ccal = (-55.85…

Q: gram sample of a compound is made up of 35.9 G of aluminum and 64.1 G of sulfur. the empirical…

Q: Express Ksp in terms of molar solubility, x, for the salts with the given formulas. AB(s) Ksp = =…

Q: Calculate the amount of fertilizer needed to meet the recommended rate for eggplants which is…

A: Recommended rate of fertilizer for eggplant = 120-60-15 Kg/ha Nitrogen = 120 Kg Phosphorus = 60 Kg…

Q: What is the primary structure of a polypeptide

A: Primary Structure: The primary structure of polypeptides is the sequence of amino acids in the…

Q: НС. енз CH -CH=CH₂₁₂ Bral сам (Bromination) Вр енз CH HC - CH - Bo Dehalogenation 11 CE CH сн ·CH· -…

Q: if you have 105 ml of a liquid with a density of 1.15 g/cm^3, how many grams do you have?

A: Formula of density would be used to calculate mass in grams .

Q: What is the order of increasing acidity for the following compounds? (least to most)

A: In this question, we will arranging all the compounds in increasing order of acidity from the least…

Q: PROBLEM 1: Complete the following table, the second row was set as an example. System # of Component…

A: To write no. of components, phases and degrees of freedom for the given systems

Q: The solvolysis reaction below gives a complex product mixture. The elimination products shown below…

Q: C5H8 isomer(s) having only secondary and quaternary carbons

A: Since the isomers of C5H8 have primary, secondary, tertiary, quaternary carbons, hence the given…

Q: Complete the following three tasks below. a. Find the approximate pKa value for each compound in the…

A: Ionic compound ===> Water soluble Non-ionic compound ====> Organically soluble

Q: A chemical reaction has an equilibrium constant of 2 × 1016. If the reaction is in equilibrium,…

Q: Which compound contains an alpha-chloro group? 0 CH3CHCICH3 0 CH3CH2CHCICOOH Option 4 Arrange the…

A: ->In nucleophilic acyl substitution reaction we see electrophilicity of carbonyl center as the…

Q: tricyanidobis(ethylenediamine)nitrosylferrate(II)

A: Given a formula name and asked its formula structure.

Q: phHệ CH 3 سار اي منهم مفقل الے۔ ph left (H3 ciz right CH₂ OM OH ؟ ko

A: The acidic strength depends upon the stability of conjugate base.Stable the conjugate base more will…

Q: Calculate the pH for a buffer made with 230.0 mL of 0.189 M furoic acid (HC5H3O3) and 20.0 mL of…

Q: A dosage descibes the amount of medication administered over a specified period of time with a…

A: In 1 day 4 dose of cephalexin must be given such that in entire one must be given 25 mg/kg of drug.

Q: A chemist prepares a solution of copper(II) sulfate (CuSO4) by measuring out 12. g of copper(II)…

Q: Equation given: AuBr(s) + 2 CN– (aq) ⇄ [Au(CN)2]– (aq) + Br– (aq) Keq = 2.02 x 1033 Ksp for…

A: Given-> AuBr(s) + 2CN-(aq) <------> [Au(CN)2]-(aq) + Br-(aq) Keq = 2.02 × 1033 Ksp(AuBr) =…

Q: If the half-cell Li(s)|Li+(aq)(1.0 M) is coupled to Standard Hydrogen Electrode, will the Li(s)…

Q: 22. The reaction conditions below are known to form substituted biphenyls. Provide a catalytic cycle…

A: Given reaction is an example of Suzuki- Miyaura cross-coupling reaction.In this reaction Pd work as…

Q: Point 1 on the vapor-liquid equilibrium diagram represents a liquid (ß) that is enriched in…

A: In the given vapor-liquid equilibrium diagram, Point 1 - Liquid β Point 4 - Liquid α Now, point 6…

Q: CuSO4 (aq) + Zm(s) - › Cu(s) + 2nSO, (ag) The single-replacement reaction above produces 161.0 g of…

Q: What are examples of amine compounds that are commonly found in nature and discuss their functions…

Q: HHO H H-C-C-C-0-C-E HHHO III! H-C-C-C-C-0-H III JI Н Н A X Y The compounds above have the same…

A: Nature of functional group in both compounds decide the properties.

Q: Which salts will be more soluble in an acidic solution than in pure water? Sn(OH)₂ AgCl CsC104…

Q: Above what Fe2+ concentration will Fe(OH), precipitate from a buffer solution that has a pH of 8.13?…

Q: What is the vapor pressure at 25.0 °C of a solution containing 165 g glucose CH₁2O6 (molar mass=…

A: here we are required to find the vapour pressure of the solution

Q: A chemist measures the energy change AH during the following reaction: 2 H₂O(1)→ 2 H₂(g) + O₂(g) ΔΗ=…

Q: List the factors that affect solubility of a solid that is being dissolved in a liquid and explain…

A: Here we have to explain the factors affecting solubility of solubility of solid in liquid.

Q: Q3/ Answer True or False for each of the following: ( 1) Salicylic acid can be prepared from…

Q: pK₂ = What is the color of this indicator in a solution with pH = 4?

Q: The gallium-67 nuclide is used in tumor diagnostic applications. This has a half-life of 78.2 hours.…

A: given, half life = 78.2 hours time = 5.00 days

Q: i) iii) iv) 24 tx کہ ان CI Br es

A: Using IUPAC rule

Q: Sodium sulfate is slowly added to a solution containing 0.0500 M Ca²+ (aq) and 0.0300 M Ag+ (aq).…

Question

Show how you would prepare the following amide starting with bromocyclohexene and
any other reagents.
a-04
Propose a mechanism for the following transformation when an ethyl magnesium
bromide in excess was reacted with the acid chloride followed by heating with
concentrated sulfuric acid.
x
x

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Show how you would accomplish the following syntheses using amides as intermediates.You may use any necessary reagents. ) pyrrolidine S N@ethylpyrrolidine
Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. c) m-bromoaniline
Show how you would accomplish the following syntheses using amides as intermediates.You may use any necessary reagents.(a) benzoic acid S benzyldimethylamine
Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. (c) m-bromoaniline (d) m-aminobenzoic acid
Show how you would prepare the following amide starting with bromocyclohexene and any other reagents.
Show how to synthesize the following amines from the indicated starting materials byacylation–reduction. b) N-benzylaniline from aniline
Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials.(a) anilin
Show how you would use appropriate acyl chlorides and amines to synthesize thefollowing amides.(a) N,N-dimethylacetamide (b) acetanilide (PhNHCOCH3)(c) cyclohexanecarboxamide (d)
Show how you would use appropriate acyl chlorides and amines to synthesize thefollowing amides.(a) N,N-dimethylacetamide (b) acetanilide (PhNHCOCH3)
Propose mechanisms for the conversion of A to B and of B to C. What is the function of sodium amide in each reaction?
Show how to synthesize the following amines from the indicated starting materials byreductive amination. (±)-amphetamine 1-phenylpropan-2-one
Show how you would use bromination followed by amination to synthesize the followingamino acids. (b) leucine (c) glutamic acid