Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. (c) m-bromoaniline (d) m-aminobenzoic acid

Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. (c) m-bromoaniline (d) m-aminobenzoic acid

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.SE: Something Extra

Problem 37MP

See similar textbooks

Related questions

Q: 1. Which are the starting materials used to synthesize the given compound through reductive…

Q: Treating trimethylamine with 2-chloroethyl acetate gives acetylcholine as its chloride.…

A: Trimethylamine reacts with 2-chloroethylacetate by SN2 mechanism. Thus the bond breaking and bond…

Q: Give the products expected when the following tertiary amines are treated with a peroxyacid and…

Q: Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You…

A: Preparation of c) m-bromoaniline : Benzene is taken as the starting material. The correct sequence…

Q: Show how you would accomplish the following syntheses using amides as intermediates.You may use any…

A: The structure of benzoic acid is shown below: The structure of benzyldimethylamine is:

Q: Methamphetamine is a long-lasting, potent stimulant sold as a street drug. The synthesis is quite…

A: According to the question, we need to synthesis Methamphetamine (a street drug) from the given…

Q: Explain why a secondary amine forms a nitrosamine rather than a diazonium salt when it reacts with…

Q: In the 1880's, Acetanilide, sold under the name Antifebrin, was widely used as a pain reliever and…

A: Here we have to write the mechanism of acid catalyzed hydrolysis of acetanilide and synthesis of…

Q: Show how Gabriel syntheses are used to prepare the following amines.(a) benzylamine

Q: Why does p-nitroacetanilide recrystallize in ethanol, but the o-acetanilide remains in the filtrate…

A: The separation of p-nitroacetanilide and o-nitroacetanilide can be done on the basis of its…

Q: Show how you might utilize the reduction of an amide, oxime, or a nitrile to carry out each of the…

Q: Show how to synthesize the following amines from the indicated starting materials…

A: Given The given organic compounds are N-butylpiperidine and piperidine.

Q: H,N NH COC,H; C. C,H5. 1. C,H,O¯N * 2. H,0 9. 2) \4. C=0 O + 2C,H;OH C,H, NH C,H; COC,H, H,N…

Q: The two most general amine syntheses are the reductive amination of carbonyl compounds and the…

A: Amines are the compounds that have NH2 group present in it. The lone pair of nitrogen can be donated…

Q: Show how you would prepare the following amide starting with bromocyclohexene and any other…

A: In this question, we will see the reagents for the preparing final product from the starting…

Q: Give the products expected when the following tertiary amines are treated with a peroxyacid and…

A: INTRODUCTION: Cope elimination is defined as the reaction in which amine to oxidised to N-oxide, on…

Q: Rank the following compounds in order of increasing basicity: L p-nitroaniline H.…

A: Basicity of a molecule is the tendency to donate the lone pair of electrons. Electron withdrawing…

Q: Show how to synthesize the following amines from the indicated starting materials below. Each of the…

A: The question is based on the concept of chemical reactions. we have to convert benzene to meta-bromo…

Q: Reduction of an alkyl azide results in the formation of —-. A. an imine B. an oxime C. a tertiary…

A: Alkyl azide have general formula R-N3

Q: Show how to synthesize the following amines from the indicated starting materials…

A: INTRODUCTION: Acylation is defined as the addition of acyl group to a compound.The compound which…

Q: Show how to synthesize the following amines from the indicated starting materials.(a)…

A: Given reactions, (a) N-cyclopentylaniline from aniline (b) N-ethylpyrrolidine from pyrrolidine

Q: - How would you prepare the following amines, using both Hofmann and Curtius rearrangements on a…

A: The Hofmann and Curtius rearrangement involves the conversion of carboxylic acid to an amine. The…

Q: Bucetin is a pain-relieving drug similar to phenacetin that was also banned due to its carcinogenic…

A: In Bucetin, the ether group is converted into alcohol and the hydroxyl group is converted to halide…

Q: „CHO NH3 H2. Ni A -H20 60 °C, 90 atm CI

A: Since the N in NH3 is having lone pair electron and C attached to O in the benzene reactant is…

Q: -NH -OEt H2N 1. EtO Na* 2 CH,CH2OH 2. H,0 - NH -OEt H,N Barbiturates are prepared by treating a…

A: Solution:

Q: Following is a series of anorexics (appetite suppressants). As you study their structures, you will…

A: Clobenzorex is a compound is a type of a drug which used to suppress a person appetite, this drug is…

Q: Prozac may be prepared via a Mannich reaction using which amine? Benzylamine Methylamine Ethylamine…

A: A chemical reaction in which organic compounds take part is called organic reactions. Organic…

Q: Show how you would prepare the following amide starting with bromocyclohexene and any other…

Q: Show how to synthesize the following amines from the indicated starting materials byreductive…

A: To synthesize N-Cyclohexylaniline from cyclohexanone The primary amine can be synthesized from the…

Q: A compound of formula C11H16N2 gives the IR, 1H NMR, and 13C NMR spectra shown. The proton NMR peak…

Q: Reduction of aromatic nitro-compounds using Sn and HCl gives :Select one a. aromatic secondary…

A: Given, Reduction of aromatic nitro compounds using Sn and HCl gives = ? Sn/HCl - is a reducing agent…

Q: Propose a synthesis for diphenhydramine starting from benzophenone, benzoic acid, and 2-(N,…

A: Synthetic method for diphenhydramine: Benzophenone undergoes reduction using sodium borohydride on…

Q: Show how to synthesize the following amines from the indicated starting materials byreductive…

A: Amines are the organic molecule contains one or more nitrogen atom. Reductive amination is the…

Q: Synthesis of amides from acid chlorides is an effective tool for creating many different compounds.…

A: The question is based on the concept of organic reactions. we have to convert the given reactant…

Q: Show how butylamine can be prepared via the Gabriel Amine Synthesis.

A: Welcome to bartleby ! We have to synthesised butylamine via Gabriel Amine Synthesis.

Q: Show how to synthesize the following amines from the indicated starting materials byreductive…

A: Concept introduction: The reaction of a primary amine with either aldehydes or ketones in the…

Q: Following are structural formulas for two more widely used sulfonylurea hypoglycemic agents.Show how…

A: To synthesize Gliclazide, diethyl carbonate can be treated with the hydrazine to make the carbamic…

Q: Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You…

A: The structure of p-bromoaniline is shown below.

Q: Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You…

A: Nitration is chemical process in which nitro group is introduced into an organic compound.

Q: Give the products expected when the following tertiary amines are treated with a peroxyacid and…

A: The formation of expected products, when tertiary amines are reacted with a peroxy acid and heated…

Q: Following is a series of anorexics (appetite suppressants). As you study their structures, you will…

A: A synthesis for a given compound has to be given, The given compound is,

Q: Although acetanilide and phenacetin are not appreciably acidic, aceta- minophen (like aspirin) is a…

A: Carboxylic acids and phenols are acidic than water. These react with sodium hydroxide to form sodium…

Q: Show how to synthesize the following amines from the indicated starting materials byreductive…

A: It is organic chemical reactions shown below

Q: Show how you would prepare the following amide starting with bromocyclohexene and any other…

A: Here we are required to show the mechanism for the reaction

Question

Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene and
toluene as your aromatic starting materials.
(c) m-bromoaniline (d) m-aminobenzoic acid

Definition Definition Organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Aromatic organic compounds, also called arenes, are an important class of hydrocarbons under the branch of organic chemistry.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. p-bromoaniline
Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials.(a) anilin
Show how to prepare the following aromatic amines by aromatic nitration, followed by reduction. You may use benzene andtoluene as your aromatic starting materials. c) m-bromoaniline
Show how to synthesize the following amines from the indicated starting materials byacylation–reduction. b) N-benzylaniline from aniline
The two most general amine syntheses are the reductive amination of carbonyl compounds and the reduction of amides.Show how these techniques can be used to accomplish the following syntheses.(a) benzoic acid S benzylamine (b) benzaldehyde S benzylamine(c) pyrrolidine S N@ethylpyrrolidine (d) cyclohexanone S N@cyclohexylpyrrolidine(e) HOOC¬(CH2)3 ¬COOH S pentane@1,5@diamine (cadaverine)
Give the products expected when the following tertiary amines are treated with a peroxyacid and heated.N-ethylpiperidine
Rank the following amines based on basicity Rationalize the electronic effects responsible for the basicity of amines
Give the products expected when the following tertiary amines are treated with a peroxyacid and heated.cyclohexyldimethylamine
Account for the following :(i) Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).(ii) Aniline does not undergo Friedel – Crafts reaction.(iii) (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Benzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. The derivative consisting of primary amines is insoluble in dilute NaOH.RightFalse
Following is an outline of a synthesis of the bronchodilator carbuterol, a beta-2 adrenergic blocker with high selectivity for airway smooth muscle receptors. Q.Suggest a structural relationship between carbuterol and ephedrine
Which of these statements is NOT true about the reaction of amines with a cyclic anhydride like phthalic anhydride? a. Dimethylamine will give a cyclic imide product. b. Aniline will give a cyclic imide product. c. Triethylamine will give a cyclic imide product. d. The reaction undergoes a nucleophilic acyl substitution mechanism.