Show that if it can be assumed that there is a pre-equilibrium involving step v=k₂K[CH₂CICH₂OH][OH-]/ce, (1), the rate of formation of ethylene oxide is v= where K is the equilibrium constant for the first step and k, is the rate constant ons for the second step. d lo notioqu

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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter13: Chemical Kinetics
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Problem 13.49QE: When formic acid is heated, it decomposes to hydrogen and carbon dioxide in a first-order decay....
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Show that if it can be assumed that there is a pre-equilibrium involving step
= k₂K[CH₂CICH₂OH][OH-]/ce,
(1), the rate of formation of ethylene oxide is v=
where K is the equilibrium constant for the first step and k, is the rate constant
for the second
step.
rottsdy 1A for!!
action consists of a pre-equilibrium sten
nog sist art
sbrolib
Transcribed Image Text:Show that if it can be assumed that there is a pre-equilibrium involving step = k₂K[CH₂CICH₂OH][OH-]/ce, (1), the rate of formation of ethylene oxide is v= where K is the equilibrium constant for the first step and k, is the rate constant for the second step. rottsdy 1A for!! action consists of a pre-equilibrium sten nog sist art sbrolib
formation of O₂ is
E17E.2(b) The mechanism for the reaction between 2-chloroethanol,
CH₂CICH₂OH, and hydroxide ions in aqueous solution to form ethylene
oxide, (CH₂CH₂)O, is thought to consist of the steps
szolulls to noites
bas colo
(1) CH₂CICH₂OH+OHCH₂CICH₂O
Yo Lleg
HAHA (19tistor ATLE
+ H₂Orig
2 noitara
(pau Isu) lia
(2) CH₂CICH₂O → (CH₂CH₂)O+CIl sdi mori bevosta HD di
vistasmala od 101 21nstagoo
molect
boranom ((seenesie 101 A
-252 clipalo
Transcribed Image Text:formation of O₂ is E17E.2(b) The mechanism for the reaction between 2-chloroethanol, CH₂CICH₂OH, and hydroxide ions in aqueous solution to form ethylene oxide, (CH₂CH₂)O, is thought to consist of the steps szolulls to noites bas colo (1) CH₂CICH₂OH+OHCH₂CICH₂O Yo Lleg HAHA (19tistor ATLE + H₂Orig 2 noitara (pau Isu) lia (2) CH₂CICH₂O → (CH₂CH₂)O+CIl sdi mori bevosta HD di vistasmala od 101 21nstagoo molect boranom ((seenesie 101 A -252 clipalo
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