Silicon tetrachloride (SiCl,) and trichlorosilane (SiHCl3 ) are both starting materials for the production of electronics-grade silicon. Calculate the densities of pure SiCl4 and pure SIHCI, vapor at 96°C and 725 torr. Density of SiCl4 vapor = Density of SIHC13 vapor= g/L

Silicon tetrachloride (SiCl,) and trichlorosilane (SiHCl3 ) are both starting materials for the production of electronics-grade silicon. Calculate the densities of pure SiCl4 and pure SIHCI, vapor at 96°C and 725 torr. Density of SiCl4 vapor = Density of SIHC13 vapor= g/L

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter5: Gases

Section: Chapter Questions

Problem 74E: Urea (H2NCONH2) is used extensively as a nitrogen source in fertilizers. It is produced commercially...

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5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.
5-107 If 60.0 g of NH3 occupies 35.1 L under a pressure of 77.2 in. Hg, what is the temperature of the gas, in °C?
5-54 Automobile air bags are inflated by nitrogen gas. When a significant collision occurs, an electronic sensor triggers the decomposition of sodium azide to form nitrogen gas and sodium metal. The nitrogen gas then inflates nylon bags, which protect the driver and front-seat passenger from impact with the dashboard and windshield. What volume of nitrogen gas measured at 1 atm and 27°C is formed by the decomposition of 100. g of sodium azide?
The gas in the discharge cell of a laser contains (in mole percent) 11% CO2, 5.3% N2, and 84% He. (a) What is the molar mass of this mixture? (b) Calculate the density of this gas mixture at 32C and 758 mm Hg. (c) What is the ratio of the density of this gas to that of air (MM=29.0g/mol)at the same conditions?
5-37 A sample of a gas at 77°C and 1.33 atm occupies a volume of 50.3 L. (a) How many moles of the gas are present? (b) Does your answer depend on knowing what gas it is?
Exhaled air contains 74.5% N2, 15.7% O2, 3.6% CO2, and 6.2% H2O (mole percent). (a) Calculate the molar mass of exhaled air. (b) Calculate the density of exhaled air at 37C and 757 mm Hg and compare the value you obtained with that of ordinary air (MM=29.0g/mol) under the same conditions.
97 Homes in rural areas where natural gas service is not available often rely on propane to fuel kitchen ranges. The propane is stored as a liquid, and the gas to be burned is produced as the liquid evaporates. Suppose an architect has hired you to consult on the choice of a propane tank for such a new home. The propane gas consumed in 1.0 hour by a typical range burner at high power would occupy roughly 165 L at 25°C and 1.0 atm, and the range chosen by the client will have six burners. If the tank under consideration holds 500.0 gallons of liquid propane, what is the minimum number of hours it would take for the range to consume an entire tankful of propane? The density of liquid propane is 0.5077 kg/L.
5-25 A gas in a bulb as in Figure 5-3 registers a pressure of 833 mm Hg in the manometer in which the reference arm of the U-shaped tube (A) is sealed and evacuated. What will the difference in the mercury levels be if the reference arm of the U-shaped tube is open to atmospheric pressure (760 mm Hg)?
Methane (CH4) gas flows into a combustion chamber at a rate of 200. L/min at 1.50 atm and ambient temperature. Air is added to the chamber at 1.00 atm and the same temperature, and the gases are ignited. a. To ensure complete combustion of CH4 to CO2(g) and H2O(g), three times as much oxygen as is necessary is reacted. Assuming air is 21 mole percent O2 and 79 mole percent N2, calculate the flow rate of air necessary to deliver the required amount of oxygen. b. Under the conditions in part a, combustion of methane was not complete as a mixture of CO2(g) and CO(g) was produced. It was determined that 95.0% of the carbon in the exhaust gas was present in CO2. The remainder was present as carbon in CO. Calculate the composition of the exhaust gas in terms of mole fraction of CO, CO2, O2, N2, and H2O. Assume CH4 is completely reacted and N2 is unreacted.
One type of gas mixture used in anesthesiologyis a 50%/50% mixture (by volume) of nitrous oxide (N2O) and oxygen(O2), which can be premixed and kept in a cylinder for later use.Because these two gases don’t react chemically at or below 2000 psi, attypical room temperatures they form a homogeneous single gas phase,which can be considered an ideal gas. If the temperature drops below-6C, however, N2O may begin to condense out of the gas phase. Thenany gas removed from the cylinder will initially be nearly pure O2; asthe cylinder empties, the proportion of O2 will decrease until the gascoming from the cylinder is nearly pure N2O. In a hospital, pure oxygen may be delivered at 50 psi (gaugepressure) and then mixed with N2O. What volume of oxygen at 20Cand 50 psi (gauge pressure) should be mixed with 1.7 kg of N2O toget a 50%/50% mixture by volume at 20C? (a) 0.21 m3; (b) 0.27 m3;(c) 1.9 m3; (d) 100 m3
One type of gas mixture used in anesthesiologyis a 50%/50% mixture (by volume) of nitrous oxide (N2O) and oxygen(O2), which can be premixed and kept in a cylinder for later use.Because these two gases don’t react chemically at or below 2000 psi, attypical room temperatures they form a homogeneous single gas phase,which can be considered an ideal gas. If the temperature drops below-6C, however, N2O may begin to condense out of the gas phase. Thenany gas removed from the cylinder will initially be nearly pure O2; asthe cylinder empties, the proportion of O2 will decrease until the gascoming from the cylinder is nearly pure N2O. In another test, the valve of a 500 L cylinder full of the gas mixture at 2000 psi (gauge pressure) is opened wide so that the gas rushes out of the cylinder very rapidly. Why might some N2O condense during this process? (a) This is an isochoric process in which the pressure decreases, so the temperature also decreases. (b) Because of the rapid expansion, heat is…
Chlorine gas (Cl2) can be prepared on a small scale according to the following balanced equation:MnO2(s) + 4 HCl(aq) -----> MnCl2(aq) + 2 H2O(l) + Cl2(g)If you perform this reaction with 10.0 grams of HCl and excess MnO2, what volume of Cl2, measured at 740 mm Hg and collected over water 27.0oC, can be obtained? (The vapor pressure of water at 27oC = 26.7 mm Hg)