One type of gas mixture used in anesthesiologyis a 50%/50% mixture (by volume) of nitrous oxide (N2O) and oxygen(O2), which can be premixed and kept in a cylinder for later use.Because these two gases don’t react chemically at or below 2000 psi, attypical room temperatures they form a homogeneous single gas phase,which can be considered an ideal gas. If the temperature drops below-6C, however, N2O may begin to condense out of the gas phase. Thenany gas removed from the cylinder will initially be nearly pure O2; asthe cylinder empties, the proportion of O2 will decrease until the gascoming from the cylinder is nearly pure N2O. In another test, the valve of a 500 L cylinder full of the gas mixture at 2000 psi (gauge pressure) is opened wide so that the gas rushes out of the cylinder very rapidly. Why might some N2O condense during this process? (a) This is an isochoric process in which the pressure decreases, so the temperature also decreases. (b) Because of the rapid expansion, heat is removed from the system, so the internal energy and temperature of the gas decrease. (c) This is an isobaric process, so as the volume increases, the temperature decreases proportionally. (d) With the rapid expansion, the expanding gas does work with no heat input, so the internal energy and temperature of the gas decrease.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
Section: Chapter Questions
Problem 79AP
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One type of gas mixture used in anesthesiology
is a 50%/50% mixture (by volume) of nitrous oxide (N2O) and oxygen
(O2), which can be premixed and kept in a cylinder for later use.
Because these two gases don’t react chemically at or below 2000 psi, at
typical room temperatures they form a homogeneous single gas phase,
which can be considered an ideal gas. If the temperature drops below
-6C, however, N2O may begin to condense out of the gas phase. Then
any gas removed from the cylinder will initially be nearly pure O2; as
the cylinder empties, the proportion of O2 will decrease until the gas
coming from the cylinder is nearly pure N2O. In another test, the valve of a 500 L cylinder full of the gas
mixture at 2000 psi (gauge pressure) is opened wide so that the gas
rushes out of the cylinder very rapidly. Why might some N2O condense
during this process? (a) This is an isochoric process in which
the pressure decreases, so the temperature also decreases. (b) Because
of the rapid expansion, heat is removed from the system, so the internal
energy and temperature of the gas decrease. (c) This is an isobaric
process, so as the volume increases, the temperature decreases
proportionally. (d) With the rapid expansion, the expanding gas does
work with no heat input, so the internal energy and temperature of the
gas decrease.

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