Sodium chloride is added slowly to a solution that is 0.010 M in Cu*, Ag*, and Au*. Because solubility "rules" are generalizations, we don't use solubility rules when we have the specific Ksp data available. Instead, here, we can just use the Ksp value for CuCl which is 1.9 x 10-7, for AgCl is 1.6 x 10-10, and for AuCl is 2.0 × 10-13. Based on these specific Ksp values, which compound will precipitate first?

Fundamentals Of Analytical Chemistry
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Chapter10: Effect Of Electrolytes On Chemical Equilibria
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Sodium chloride is added slowly to a solution that is 0.010 M in Cu*, Ag*, and Au*.
Because solubility "rules" are generalizations, we don't use solubility rules when we
have the specific Ksp data available. Instead, here, we can just use the Ksp value for
CuCl which is 1.9 x 10-7, for AgCl is 1.6 x 10-10, and for AuCl is 2.0 × 10-13. Based on
these specific Ksp values, which compound will precipitate first?
Transcribed Image Text:Sodium chloride is added slowly to a solution that is 0.010 M in Cu*, Ag*, and Au*. Because solubility "rules" are generalizations, we don't use solubility rules when we have the specific Ksp data available. Instead, here, we can just use the Ksp value for CuCl which is 1.9 x 10-7, for AgCl is 1.6 x 10-10, and for AuCl is 2.0 × 10-13. Based on these specific Ksp values, which compound will precipitate first?
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