solution contains 0.25 M Ni(NO3)2 and 0.25 M Cu(NO3)2. A. Can the metal ions be separated by slowly adding Na2CO3 aq solution? Assume that for successful separation 99% of the metal ion must be precipitated before the other metal ion begins to precipitate, and assume no volume change on addition of Na2CO3 solution. Pls show step by step.    Ksp  of CuCO3 = 1.4 x10-10    Ksp  of NiCO3 = 1.42X 10-7 B.  If you need to redissolve the salt that was first precipitated, what

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Chapter16: Solubility And Complex Ion Equilibria
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Problem 60E: A solution contains 0.25 M Ni(NO3)2 and 0.25 M Cu(NO3)2. Can the metal ions be separated by slowly...
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A solution contains 0.25 Ni(NO3)2 and 0.25 Cu(NO3)2.

A. Can the metal ions be separated by slowly adding Na2CO3 aq solution? Assume that for successful separation 99% of the metal ion must be precipitated before the other metal ion begins to precipitate, and assume no volume change on addition of Na2CO3 solution. Pls show step by step.

   Ksp  of CuCO3 = 1.4 x10-10

   Ksp  of NiCO3 = 1.42X 10-7

B.  If you need to redissolve the salt that was first precipitated, what pH will you use and why ?

 

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