Suggest a method by which Ni2+ can be precipitated homogeneously as NiS. a. Add sodium sulfste to the solution to precipitate NiSO4. Heat the nickel(II) sulfate to liberate O2 and yield pure NiS. b. The slow hydrolysis of thioacetamide can be used to generate a source of hydrogen sulfide gas, which provides the S²- to complex with the Ni2+. c. Add thiosulfuric acid to the solution to react with Ni2+ and precipitate NiS. d. Heat S8 in the presence of Ni2+, in an inert atmosphere, to produce NiS.

Chemical Principles in the Laboratory
11th Edition
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Chapter27: Relative Stabilities Of Complex Ions And Precipitates Prepared From Solutions Of Copper(ii)
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Suggest a method by which Ni2+ can be precipitated homogeneously as NiS.

a. Add sodium sulfste to the solution to precipitate NiSO4. Heat the nickel(II) sulfate to liberate O2 and yield pure NiS.

b. The slow hydrolysis of thioacetamide can be used to generate a source of hydrogen sulfide gas, which provides the S²- to complex with the Ni2+.

c. Add thiosulfuric acid to the solution to react with Ni2+ and precipitate NiS.

d. Heat S8 in the presence of Ni2+, in an inert atmosphere, to produce NiS.

 

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