You wish to measure the iron content of the well water on the new property you are about to buy. You prepare a reference standard Fe3+ solution with a concentration of 7.22 × 10-4 M. You treat 11.0 mL of this reference with HNO, and excess KSCN to form a red complex and dilute the reference to 60.0 mL. The diluted reference is placed in a cell with a 1.00-cm light path. You then take 10.0 mL of the well water, treat with HNO, and excess KSCN, and dilute to 100.0 mL. This diluted sample is placed in a variable pathlength cell. The absorbance of the reference and the sample solutions match when the pathlength is 3.93 cm. What is the concentration of iron in the well water? For each solution, the zero is set with a blank. [Fe+]well water M

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.14QAP
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You wish to measure the iron content of the well water on the new property you are about to buy. You prepare a reference
standard Fe3+ solution with a concentration of 7.22 × 10-4 M. You treat 11.0 mL of this reference with HNO, and excess
KSCN to form a red complex and dilute the reference to 60.0 mL. The diluted reference is placed in a cell with a 1.00-cm
light path. You then take 10.0 mL of the well water, treat with HNO, and excess KSCN, and dilute to 100.0 mL. This diluted
sample is placed in a variable pathlength cell. The absorbance of the reference and the sample solutions match when the
pathlength is 3.93 cm. What is the concentration of iron in the well water? For each solution, the zero is set with a blank.
[Fe3+]well
М
Jwell water
Transcribed Image Text:You wish to measure the iron content of the well water on the new property you are about to buy. You prepare a reference standard Fe3+ solution with a concentration of 7.22 × 10-4 M. You treat 11.0 mL of this reference with HNO, and excess KSCN to form a red complex and dilute the reference to 60.0 mL. The diluted reference is placed in a cell with a 1.00-cm light path. You then take 10.0 mL of the well water, treat with HNO, and excess KSCN, and dilute to 100.0 mL. This diluted sample is placed in a variable pathlength cell. The absorbance of the reference and the sample solutions match when the pathlength is 3.93 cm. What is the concentration of iron in the well water? For each solution, the zero is set with a blank. [Fe3+]well М Jwell water
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