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- suggest a plausible arrow-pushing mechanism for the formation of a covalent adduct between the suicide inhibitor 5-trifluoromethyluridylic acid and thymidylate synthase that involves the active_site thiolate.if possible please post links used for summary a. Summarize and briefly explain the chemical interaction between EDC and NHS in Electrochemical Biosensing (CHEMICAL NAME: N-ethyl-N′-(3-(dimethylamino)propyl)carbodiimide/N-hydroxysuccinimide) b. Summarize and briefly explain the chemical interaction between Biotin & Avidin in Electrochemical BiosensingGive the synthesis of Caffeine from inosine monophosphate.
- What are the experimental procedures and the laboratory equipments needed to be used in the removing of carbon dioxide and Nucleophilic addition on the nitrogen of isoxazoline that will have a product of protein that contain native serine residues by the reaction of oxazetidine-containing peptides and α-ketoacidGive brief information about the synthesis methods of amides. Show the reaction mechanism for obtaining benzamide from benzoyl chloride.What is the purpose of adding sodium carbonate in the mixture of water and water- soluble components obtained from the solid-liquid extraction step of isolation of alkaloids from tea leaves? A.Increases the solubility of alkaloids in water thus ensuring maximum yield B.deprotonates tannins so that they will remain in the aqueous layer during liquid-liquid extraction C.'hydrolyses cellulose thus separating it along with other water-soluble components D.protonates the alkaloid to make the solution acidic
- Provide the aspirin synthesis mechanism.Bradykinin is a linear nonapeptide released by blood plasma globulin in response to a wasp sting. It is a very potent pain-causing agent. Its constituent amino acids are 2R, G, 2F, 3P, S. The sue of 2,4-dinitrofluorobenzene and carboxypeptidase shows that both terminal residues are arginine. Partial hydrolysis of bradykinin gives the following di- and tripeptides: FS + PGF +PP + SPF + FR + RPBriefly explain about Degradation of azo dyes , include aerobic, anaerobic etc.