Chapter34: Miscellaneous Separation Methods
Section: Chapter Questions
Problem 34.7QAP
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Question
The phase diagram for SO2 is shown here. (a) What does
this diagram tell you about the enthalpy change in the
reaction SO2(l) ---->SO2(g)? (b) Calculate the equilibrium
constant for this reaction at 100 °C and at 0 °C.
(c) Why is it not possible to calculate an equilibrium constant
between the gas and liquid phases in the supercritical
region? (d) At which of the three points marked in red
does SO2(g) most closely approach ideal-gas behavior?
(e) At which of the three red points does SO2(g) behave
least ideally?
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