The arsenic in a 1.209-g sample of a pesticide was converted to H3 AsO4 by suitable treatment. The acid was then neutralized, and 43.00 ml of 0.05829 M AgNO3 was added to precipitate the arsenic quantitatively as Ag3 AsO4. The excess Ag in the filtrate and in the washings from the precipitate was titrated with 9.83 mL of 0.1000 M KSCN, and the reaction was Ag+ + SCN → AGSCN Find the percentage of As2 O3 in the sample. Percentage of As2 O3 = %

Fundamentals Of Analytical Chemistry
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Author:Skoog
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Chapter13: Titrations In Analytical Chemistry
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The arsenic in a 1.209-g sample of a pesticide was converted to H3 AsO4 by suitable treatment. The acid was then neutralized, and
43.00 mL of 0.05829 M AgN03 was added to precipitate the arsenic quantitatively as Ag3 AsO4. The excess Ag in the filtrate and in
the washings from the precipitate was titrated with 9.83 mL of 0.1000 M KSCN, and the reaction was
Ag+ + SCN → AgSCN
Find the percentage of As2 O3 in the sample.
Percentage of As2O3 =
%
Transcribed Image Text:The arsenic in a 1.209-g sample of a pesticide was converted to H3 AsO4 by suitable treatment. The acid was then neutralized, and 43.00 mL of 0.05829 M AgN03 was added to precipitate the arsenic quantitatively as Ag3 AsO4. The excess Ag in the filtrate and in the washings from the precipitate was titrated with 9.83 mL of 0.1000 M KSCN, and the reaction was Ag+ + SCN → AgSCN Find the percentage of As2 O3 in the sample. Percentage of As2O3 = %
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