The average bond enthalpies of the C—F and C—Cl bondsare 485 kJ/mol and 328 kJ/mol, respectively. (a) What isthe maximum wavelength that a photon can possess andstill have sufficient energy to break the C—F and C—Clbonds, respectively? (b) Given the fact that O2, N2, andO in the upper atmosphere absorb most of the light withwavelengths shorter than 240 nm, would you expect thephotodissociation of C—F bonds to be significant in thelower atmosphere?

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Chapter20: The Representative Elements
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Problem 110CP
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The average bond enthalpies of the C—F and C—Cl bonds
are 485 kJ/mol and 328 kJ/mol, respectively. (a) What is
the maximum wavelength that a photon can possess and
still have sufficient energy to break the C—F and C—Cl
bonds, respectively? (b) Given the fact that O2, N2, and
O in the upper atmosphere absorb most of the light with
wavelengths shorter than 240 nm, would you expect the
photodissociation of C—F bonds to be significant in the
lower atmosphere?

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