Chemical Kinetics The decomposition of SO,Cl, is first order in So,Cl,and has a rate constant of 1.42x10-4 s-1.a) If the initial concentration of SO,CI, is 1.00 M,how long will it take for the concentration todecrease to 0.78 M?b) If the initial concentration of SO,Cl, is 0.150 M,what is the concentration of SO,CI, after 5.00x102 s?

a) Given in the question,K= 1.42 ×10-4 s-1Initial concentration of SO2Cl2, [SO2Cl2]i = 1.00MFinall…

The decomposition of SO,Cl, is first order in SO,CI, and has a rate constant of 1.42x10-4 s-1. a) If the initial concentration of SO,Cl, is 1.00 M, how long will it take for the concentration to decrease to 0.78 M?

The decomposition of SO,Cl, is first order in SO,CI, and has a rate constant of 1.42x10-4 s-1. a) If the initial concentration of SO,Cl, is 1.00 M, how long will it take for the concentration to decrease to 0.78 M?

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter11: Rate Of Reaction

Section: Chapter Questions

Problem 21QAP: The reaction ICl(g)+12 H2(g)12 I2(g)+HCl(g)is first-order in both reactants. At a certain...

See similar textbooks

Related questions

Q: The rate constant for this second-order reaction is 0.480 M-' · s-' at 300 °C. A – products How…

Q: The rate constant for this second-order reaction is 0.170 M.s at 300 °C. A products How long, in…

A: To solve this problem we will use integrated rate law for the second-order reaction Which is given…

Q: 9.) A reaction is known to be second order with respect to A. If you start with a 1.0 M solution,…

A: Since we know that the relationship between the concentration and time for a second order reaction…

Q: 1. The decomposition of SO,Cl, is first order in So,CI, and has a rate constant of 1.42×10-4 s-1. a)…

Q: A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and…

Q: Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and…

A: The rate expression for the given reaction in accordance with the given condition is shown as…

Q: The rate constant for this second-order reaction is 0.730 M-1 - s' at 300 °C. A– products How long,…

A: The order of the reaction is second and the value of the rate constant is = 0.730 M-1 . s-1 The…

Q: Determine the half life of a reaction with rate constant, k= 0.00504 M/s if the initial…

A: We have initial concentration as 0.321 M, and rate constant value as 0.00504 M/s . We have to…

Q: (6) 2. The half-life for a reaction is 726 s. Starting with a concentration of 0.6000 M, how long…

A: We have given that The half-life for a reaction is 726 s. Starting with a concentration of 0.6000…

Q: In a study of the gas phase decomposition of sulfuryl chloride at 600 K SO̟Cl,(g)SO,(g) + Cl½(g) the…

A: There are various kinds of rate of reaction on basis of the dependance to the reactant…

Q: The rate constant for this second-order reaction is 0.780 M-·s- at 300 °C. A → products How long, in…

Q: The decomposition of nitramide in aqueous solution at 25 °C NH,NO,(aq) → N,0(g) + H20(1) is first…

Q: The rate constant for this second-order reaction is 0.750 M- •s' at 300 °C. A products How long, in…

A: Given Reaction :- A ----> products Second Order Reaction => K t = […

Q: The decomposition of SO,Cl, is first order in So,Cl, and has a rate constant of 1.42x10-4 s-1. a) If…

A: Given the first-order decomposition of SO2Cl2

Q: The decomposition of N,O5 to NO, and O, is first order, with a rate constant of 4.80 x 10-4/s at 45°…

A: Answer: a) 1.11×10^-2 mol/L, b) 1043.5 s, last part) 1064.4 s

Q: Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and…

A: Here, rate law can be said as :r = KA' B° C2r = KA'C2 -(1)

Q: The decomposition of ammonia on a platinum surface at 856 °C NH3-1/2 N2 + 3/2 H2 is zero order in…

A: The rate of the zero-order reaction does not depend on the concentration of the reactant. For the…

Q: The rate constant for the breakdown of an isotope of iodine is first order and has a half-life of…

Q: The rate constant for this zero-order reaction is 0.0320 M s- at 300 C. A products How long (in…

A: Zero order reaction :- Reaction in which rate is independent of concentration of reactants is called…

Q: The decomposition of dinitrogen pentoxide in carbon tetrachloride solution at 30 °C N2052 NO, + ½ 02…

Q: The decomposition reaction of A to B is a second-order reaction with a half-life of 5.72x10 seconds:…

Q: The decomposition of nitramide in aqueous solution at 25 °C NH,NO,(aq)N,0(g) + H,0(I) is first order…

Q: For the reaction of BF, (g) + NH, (g) F,BNH, (g) the second-order rate constant k at 100° C is 3.41…

A: Given chemical Reaction is of 2nd order reaction. Rate constant (k) = 3.41 M-1S-1 Initial…

Q: • The decomposition of SO,Cl, is first order in S0,Cl, and it has a half-life of 4.1 hours. If you…

A: Given data contains, Half-life is 4.1 hours. Initial concentration of SO2Cl2 is 1.6×10-3 mol. Final…

Q: The hydrolysis of sucrose to form fructose and glucose is a first order reaction that has a half…

A: Given that, the hydrolysis of sucrose to form fructose and glucose is a first order reaction. The…

Q: The first-order decomposition, A → products, has a rate constant of 0.0 Starting with [A], = 0.7 M,…

A: Given that rate constant = 0.02 s-1 [A0] = 0.7 M [At] = 0.1 M

Q: 2) The reaction 2H, + NO ® H,O + 1/2 N, is first order in H, and second order in NO. The overall…

Q: Consider a hypothetical reaction between A, B, and C that is first order in A, zero order in B, and…

A: Chemical kinetics is the branch of chemistry that mainly deals with the rate of reaction and change…

Q: The concentration of some element A decreases from 0.350M to 0.212M from 2 seconds to 6 seconds in a…

A: Rate of a reaction difined by change in concentration with time.

Q: The decomposition of N,O5 to NO2 and O2 is first order, with a rate constant of 4.80 × 10“/s at…

A: Given: Order of kinetics is 1. Rate constant = 4.80 X 10-4 s-1. Initial concentration of reactant…

Q: The half-life of a reaction is 2.50 minutes when the initial concentration of A is 0.150 M. How long…

A: Applying concept of first order reaction.

Q: The gas phase decomposition of sulfuryl chloride at 600 K so̟Cl2(2)SO,(g) + Ch(g) is first order in…

A: Given;

Q: The decomposition reaction of A to B is a second-order reaction with a half-life of 6.24x102…

A: The given decomposition reaction is : Half-life of the reaction (t1/2)= 6.24 x 102 seconds The…

Q: The reaction A →B+C is known to be second order in A with a rate constant of 0.393 M min at 25 °C.…

A: in the question given second-order kinetics:- second-order kinetics is inversely proportional to the…

Q: The rate constant for this second-order reaction is 0.170 M .5 at 300 C. A products How long, in…

Q: The half-life for the decay of radium is 1620 years. What is the rate constant for this first-order…

A: The half-life of a reaction, t1/2, is defined as the amount of time required for a reactant…

Q: A reaction A + B to products is first order in A, and second order in B. If the concentration of A…

A: Given , a reaction A + B to products is first order in A, and second order in B So , rate of…

Q: A certain reaction A → products is second order with respect to A with a rate constant, k, 0.122…

A: Use relation rate constant and concentration K=2.303log[A]°/[A]÷t

Q: The first-order decomposition, A→ products, has a rate constant of 0.02 s-1. Starting with [A], =…

A: Answer :- 97.3 Second The time required the for [A]t = 0.1 M = 97.3 s…

Q: A reaction has a rate law of Rate = (1.25 M's")[A][B]. What is the rate of the reaction if [A] =…

A: To determine the rate of the reaction if [A] = 0.661 M and [B] = 0.280 M.

Q: The first-order rate constant for the decomposition of a certain drug is 0.215 /month a) if 10.0 g…

A: The question is based on the concept of chemical kinetics. we have to calculate amount of drug…

Q: The decomposition of hydrogen iodide on a gold surface at 150 °C HI(g)% H,(g) + % »(9) is zero order…

Q: The decomposition of N2O5 is a first –order reaction with a rate constant of 0.420 min-1. If the…

Q: The reaction, A → products, is known to be second order with respect to the concentration of A and…

A: The reaction taking place is given as, => A ------> Products.

Q: The reaction A → B + C is found to be zero order. If it takes 4.2 102 seconds for an initial…

A: Order of reaction = zero order Time = 4.2 ×102 sec Initial concentration = 0.58 M Final…

Q: The first-order decomposition of N2O at 1000 K has a rate constant of 0.76 s-1. If the initial…

A: Concentration of N2O after 9.6 s can be determined using the given formula,

Q: The decomposition of hydrogen iodide follows second order kinetics with a rate constant of 2.40x104…

A: Given :- Reaction is second order Initial concentration = 0.0100 M Final concentration = 0.00900 M…

Q: The decomposition of SOCI2 is first-order in SOCI2. If the half-life for the reaction is 4.1 hr, how…

A: Given :- Initial concentration of reactant = 0.36 M Final concentration of reactant = 0.045 M Half…

Q: A certain reaction A--> products is second order with respect to A. If it takes 45 min to reduce the…

Q: The decomposition of SOCl2 is first order in SOCl2 and it has a rate constant of 0.169 hr ^-1, how…

A: Given: Rate constant, k = 0.169 hr-1 Initial concentration, A0 = 0.36M Final concentration, A =…

Question

Chemical Kinetics

The decomposition of SO,Cl, is first order in So,Cl,
and has a rate constant of 1.42x10-4 s-1.
a) If the initial concentration of SO,CI, is 1.00 M,
how long will it take for the concentration to
decrease to 0.78 M?
b) If the initial concentration of SO,Cl, is 0.150 M,
what is the concentration of SO,CI, after 5.00x102 s?

Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1 : Solution :

VIEW

Step 2 : Solution :

VIEW

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The first-order rate constant for the decomposition of a certain hormone in water at 25C is 3.42104day1. (a) If a 0.0200 M solution of the hormone is stored at 25C for two months, what will its concentration be at the end of that period? (b) How long will it take for the concentration of the solution to drop from 0.0200 M to 0.00350 M? (c) What is the half-life of the hormone?
The hydrolysis of the sugar sucrose to the sugars glucose and fructose, C12H22O11+H2OC6H12O6+C6H12O6 follows a first-order rate equation for the disappearance of sucrose: Rate =k[C12H22O11] (The products of the reaction, glucose and fructose, have the same molecular formulas but differ in the arrangement of the atoms in their molecules.) (a) In neutral solution, k=2.11011s1 at 27 C and 8.51011s1 at 37 C. Determine the activation energy, the frequency factor, and the rate constant for this equation at 47 C (assuming the kinetics remain consistent with the Arrhenius equation at this temperature). (b) When a solution of sucrose with an initial concentration of 0.150 M reaches equilibrium, the concentration of sucrose is 1.65107M . How long will it take the solution to reach equilibrium at 27 C in the absence of a catalyst? Because the concentration of sucrose at equilibrium is so low, assume that the reaction is irreversible. (c) Why does assuming that the reaction is irreversible simplify the calculation in pan (b)?
The decomposition of sulfuryl chlorideSO2Cl2fur dioxide and chlorine gases is a first-order reaction. It is found that at a certain temperature, it takes 1.43 hours to decompose 0.0714 M to 0.0681 M. (a) What is the rate constant for the decomposition? (b) What is the rate of decompostion [ SO2Cl2 ]=0.0462M? (c) How long will it take to decompose SO2Cl2 so that 45% remains?
What is the difference between average rate, initial rate, and instantaneous rate?
Consider the first-order decomposition of phosgene at a certain temperature. COCl2(g)productsIt is found that the concentration of phosgene is 0.0450 M after 300 seconds and 0.0200 M after 500 seconds. Calculate the following: (a) the rate constant at the temperature of the decomposition (b) the half-life of the decomposition (c) the intial concentration of phosgene
The decomposition of hydrogen iodide on finely divided gold at 150C is zero order with respect to HI. The rate defined below is constant at 1.20 104 mol/L s. 2HI(g)AuH2(g)+I2(g)Rate=[HI]t=k=1.20104mol/Ls a. If the initial HI concentration was 0.250 mol/L, calculate the concentration of HI at 25 minutes after the start of the reaction. b. How long will it take for all of the 0.250 M HI to decompose?
Sucrose decomposes to fructose and glucose in acid solution. A plot of the concentration of sucrose as a function of time is given in the margin. What is the rate of change of the sucrose concentration over the first 2 hours? What is the rate of change over the last 2 hours? Concentration versus time for the decomposition of sucrose.
Consider the first-order decomposition reaction A+BCwhere A (circles) decomposes to B (triangles) and C (squares). Given the following boxes representing the reaction at t=2 minutes, fill in the boxes with products at the indicated time. Estimate the half-life of the reaction.
The hypothetical reaction QR+Xproductswas monitored at 27C as a function of time. The following plots are obtained: (a) Write the rate expression for the reaction. (b) What is the rate constant if the rate of the reaction is 0.29 mol/L min when [ QR ]=[ X ]=1.000M? (c) What is the half-life for the consumption of QR when [ QR ]=0.0866M? (d) If the initial concentration of [ X ]=5.00M, what is [ X ] after 4.7 min?
Butadiene, C4H6, dimerizes according to the following reaction: C4H6(g)C8H12(g)The dimerization is a second-order reaction. It takes 145 s for the concentration of C4H6 to go from 0.350 M to 0.197 M. (a) What is k for the dimerization? (b) What is the half-life of the reaction when butadiene is 0.200 M? (c) How long will it take to dimerize 28.9% of a 0.558 M sample? d) How fast is 0.128 M butadiene dimerizing?
A certain reaction has the form aAProducts At a particular temperature, concentration versus time data were collected. A plot of 1/ [A] versus Lime (in seconds) gave a straight line with a slope of 6.90 102. What is the differential rate law for this reaction? What is the integrated rate law for this reaction? What is the value of the rate constant for this reaction? If [A]0 for this reaction is 0.100 M, what is the first half-life (in seconds)? If the original concentration (at t = 0) is 0.100 M, what is the second half-life (in seconds)?
The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. At 37C, the rate constant is 4.90104min1 (a) What is the half-life of the uncoiling at 37C (normal body temperature)? (b) What is the half-life of the uncoiling if the organism has a temperature of 40C(104F)? (c) By what factor does the rate of uncoiling increase (per C) over this temperature interval?