The dimerization of butadiene 2C,H(g) C3H12(g) was studied at 500. K, and the following data were obtained: Time (s) [C.H] (mol/L) 1.6 x 10 1.5 x 10 1.3 x 10 1.1 x 10 0.68 x 10 195 604 1246 2180 6210 What is the rate law and rate constant ?

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Chapter13: Rates Of Reaction
Section: Chapter Questions
Problem 13.51QP: In experiments on the decomposition of azomethane. CH3NHCH3(g)C2H6(g)+N2(g) the following data were...
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The dimerization of butadiene
2C,H.(g) C3H12(g)
was studied at 500. K, and the following data were obtained:
[C.H] (mol/L)
1.6 x 10
1.5 x 10
1.3 x 10
1.1 x 10
0.68 x 10
Time (s)
195
604
1246
2180
6210
What is the rate law and rate constant ?
Rate = k[C4H6]^2 k= 0.028
%3D
Rate = k[C4H6]^2 k= 0.007
%3D
Rate = k[C4H6] k= 0.014
%3!
Rate = k[C4H6] k= 0.007
%3!
Rate k[C4H6]^2 k= 0.014
Rate k[C4H6] k= 0.028
%3D
Transcribed Image Text:The dimerization of butadiene 2C,H.(g) C3H12(g) was studied at 500. K, and the following data were obtained: [C.H] (mol/L) 1.6 x 10 1.5 x 10 1.3 x 10 1.1 x 10 0.68 x 10 Time (s) 195 604 1246 2180 6210 What is the rate law and rate constant ? Rate = k[C4H6]^2 k= 0.028 %3D Rate = k[C4H6]^2 k= 0.007 %3D Rate = k[C4H6] k= 0.014 %3! Rate = k[C4H6] k= 0.007 %3! Rate k[C4H6]^2 k= 0.014 Rate k[C4H6] k= 0.028 %3D
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