The electrochemical cell: SCE||H+ (a=x)|glass electrode has a potential of 0.2094 V when the solution in the right-hand compartment is a buffer of pH 4.006. The potential reading for an unknown solution measured by the same glass electrode was –0.3011 V. Calculate the pH and the hydrogen ion activity of the unknown solution. Assume a Nernstian response for the glass electrode.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter21: Potentiometry
Section: Chapter Questions
Problem 21.21QAP
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The electrochemical cell: SCE||H+
(a=x)|glass electrode
has a potential of 0.2094 V when the solution in the right-hand compartment is a
buffer of pH 4.006. The potential reading for an unknown solution measured by the
same glass electrode was –0.3011 V. Calculate the pH and the hydrogen ion activity
of the unknown solution. Assume a Nernstian response for the glass electrode.

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