The electrostatic potential maps of benzene and pyridine are shown here. Is the electrostatic potential map of pyridine consistent with the ring being activated or deactivated relative to benzene? Explain.
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- Which of the dompounds is most basic and why?Shown on the left is a cationic intermediate for the electrophilic addition of chlorine to the para position of phenol. Draw the resonance stucture that is the major contributor. Include all nonbonding electrons.Which rxn/s is/are unfavorable? Briefly explain why.
- (Give clear handwritten answer) Select option that best fit for the following reactions and explanation with mexhComplete the curved-arrow mechanism for the scheme below by adding any missing atoms, bonds, charges, nonbonding electrons, and curved arrows.Nucleophilic attack may appear to occur in two steps as shown below. The alcohol is the nucleophile in this example. It attacks a carbon with a δ+ charge. The second arrow shows the flow of negative charge. WHY is it necessary? The second arrow could be thought of as a resonance arrow. HOW?
- Give a full curved arrow mechanism for the ring-opening reaction of an epoxide in aqueousacid shown below. Show ALL non-bonded electron pairs and all non-zero formal chargeswhere applicable. (Note: you will need to redraw the structures provided in order to showthe mechanism correctly; non-bonded electron pairs have not been shown, although nonzero formal charges are included.) Be sure to show any stereochemical elements in theproduct(s) correctly.For each compound below, identify which position(s) is/are most likely to undergo an electrophilic aromatic substitution reaction based on electronic effects only.What is the exact mechanism with the arrows for the dianion becoming the ketone? Does a loss of water occur/an additional protonation?