The empirical Freundlich isotherm parameters for toluene, CeHsCH3, are k = 0.208 (g CoHsCH3)/[(g carbon)(Pa)"1 and m = 0.11. Estimate the equilibrium value of toluene in the carbon [(g CaHsCH3)/(g carbon)] if the toluene concentration is 1,500 ppm, at 25°C and 101.3 kPa.
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- Consider a body of water in equilibrium with solid calcium sulfate, CaSO4, for which Ksp = 3.0 * 10^-5 at 35 degrees C. Calculate the solubility, in g/L of calcium sulfate in water assuming that other reactions are negligible.The following synthesis reaction was conducted at 325K: A2(g) + 3B2(g) ⇌ 2AB3(g). At this temperature, KP = 5.49 x 10-6. In a 3.00L flask, 0.175atm of A2(g) and 0.410atm of B2(g) are added and allowed to reach equilibrium. Calculate the pressure of AB3(g) in the system (in atm).Calcium hydroxide is a base that does not dissolve very well in water. When saturated, a calcium hydroxide solution at 25°C contains 1,3 gram Ca(OH)2 per dm3 solution. The molar mass of Ca(OH)2 is 74,1 g×mol–1. When the Ca(OH)2 dissolves, the following reaction represents the solubility equilibrium: Ca(OH)2 (s) D Ca2+ (aq) + 2 OH– (aq) Use this information above to find the value of Ksp for Ca(OH)2 at 25°C.
- Calcium hydroxide is a base that does not dissolve very well in water. When saturated, a calcium hydroxide solution at 25°C contains 1,3 gram Ca(OH)2 per dm3 solution. The molar mass of Ca(OH)2 is 74,1 g×mol–1. When the Ca(OH)2 dissolves, the following reaction represents the solubility equilibrium: Ca(OH)2 (s) D Ca2+ (aq) + 2 OH– (aq) Use this information above to find the value of Ksp for Ca(OH)2 at 25°C. What is the pH of this saturated Ca(OH)2 solution?Consider a body of water in equilibrium with solid calcium sulfate, CaSo4, for which Ksp= 3.0 x 10^-5 at 25 degrees C. Calculate the solubility, in g/L, of calcium sulfate in water assuming that other reactions are negligible. *Estimate the temperature at which the equilibrium constant for CuSO4 ⋅ 5 H2O(s) → CuSO4(s) + 5 H2O(g) becomes 1; assume pH2O = 1 bar.
- In the gas phase reaction 2 A(g) + B(g) ⇋ 3 C (g) + 2 D (g), it was found that when 1.00 mol A, 2.00 mol B and 1.00 mol D were mixed and allowed to come to equilibrium at 25oC, the resulting mixture contained 0.9 mol C at a total pressure of 1.00 bar. Calculate the mole fractions of each species, kx, kp and ∆G0Express the equilibrium constant for N2O4(g) ⇌ 2 NO2(g) in terms of the fraction a of N2O4 that has dissociated and the total pressure p of the reaction mixture,and show that when the extent of dissociation is small, a ≪1, a is inversely proportional to the square root of the total pressure, a ∝ p-1/2.In the reaction 2A (g) + B(g)==>2C(g) + D(g), 3.00 mol A was mixed with 2 mol of B and 0.5 mol of D. The system was allowed to come to equilibrium. At equilibrium, 1.2 mol of C was present at a total pressure of 1 bar. Calculate the mole fractions of each species at equilibrium, K, and ΔGr at 298 K.
- The equilibrium constant for the gas-phase isomerization of borneol (C10H17OH) to its isomer isoborneol at 503 K is 0.106. A mixture consisting of 7.50 g of borneol and 14.0 g of isoborneol in a container of volume 5.0 dm3 is heated to 503 K and allowed to come to equilibrium. Calculate the mole fractions of the two substances at equilibrium.Bromine monochloride is synthesized using the reaction:Br2(g) + Cl2(g) <-----> 2 BrCl (g)Kp = 1.1 x 10^− 4 at 150 K1. A 199.0 L flask initially contains 0.979 kg of Br 2 and 1.075 kg of Cl 2 . Calculate the mass of BrCl 2 , in grams, that is present in the reaction mixture at equilibrium. Assume ideal gas behavior.For the gas-phase reaction 2SO2 + O2 =2SO3, the observed mole fractions for a certain equilibriummixture at 1000 K and 1767 torr are xSO2 = 0.310, xO2 = 0.250, and xSO3 = 0.440. Calculate KP at 1000 K