The energy E of the electron in a hydrogen atom can be calculated from the Bohr formula: E=- In this equation R, stands for the Rydberg energy, and n stands for the principal quantum number of the orbital that holds the electron. (You can find the value of the Rydberg energy using the Data button on the ALEKS toolbar.) Calculate the wavelength of the line in the emission line spectrum of hydrogen caused by the transition of the electron from an orbital with n= 10 to an orbital with n=9. Round your answer to 3 significant digits. U um

The energy E of the electron in a hydrogen atom can be calculated from the Bohr formula: E=- In this equation R, stands for the Rydberg energy, and n stands for the principal quantum number of the orbital that holds the electron. (You can find the value of the Rydberg energy using the Data button on the ALEKS toolbar.) Calculate the wavelength of the line in the emission line spectrum of hydrogen caused by the transition of the electron from an orbital with n= 10 to an orbital with n=9. Round your answer to 3 significant digits. U um

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter5: Quantum Mechanics And Atomic Structure

Section: Chapter Questions

Problem 44AP: The energy needed to ionize an atom of element X when it is in its most stable state is 500kJmol1 ....

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Similar questions

What major assumption (that was analogous to what had already been demonstrated for electromagnetic radiation) did de Broglie and Schrodinger make about the motion of tiny panicles?
Use the mathematical expression for the 2pz wave function of a one-electron atom (see Table 5.2) to show that the probability of finding an electron in that orbital anywhere in the x-y plane is 0. What are the nodal planes for a dxz orbital and for a dx2y2 orbital?
In 1885, Johann Balmer, a mathematician, derived the following relation for the wavelength of lines in the visible spectrum of hydrogen =364.5 n2( n2 4) where in nanometers and n is an integer that can be 3, 4, 5, . . . Show that this relation follows from the Bohr equation and the equation using the Rydberg constant. Note that in the Balmer series, the electron is returning to the n=2 level.
The cesium atom has the lowest ionization energy, 375.7kJmol1 , of all the neutral atoms in the periodic table. What is the longest wavelength of light that could ionize a cesium atom? In which region of the electromagnetic spectrum does this light fall?
When metallic sodium is dissolved in liquid sodium chloride, electrons are released into the liquid. These dissolved electrons absorb light with a wavelength near 800 nm. Suppose we treat the positive ions surrounding an electron crudely as defining a three-dimensional cubic box of edge L, and we assume that the absorbed light excites the electron from its ground state to the first excited state. Calculate the edge length L in this simple model.
Quantum mechanics predicts that the energy of the ground state of the H atom is 13.6eV . Insight into the magnitude of this quantity is gained by considering several methods by which it can be measured. (a) Calculate the longest wavelength of light that will ionize H atoms in their ground state. (b) Assume the atom is ionized by collision with an electron that transfers all its kinetic energy to the atom in the ionization process. Calculate the speed of the electron before the collision. Express your answer in meters per second (ms1) and miles per hour (milesh1) . (c) Calculate the temperature required to ionize a H atom in its ground state by thermal excitation. (Hint: Recall the criterion for thermal excitation of an oscillator in Planck’s theory of blackbody radiation is that hvkBT .)
The energy needed to ionize an atom of element X when it is in its most stable state is 500kJmol1 . However, if an atom of X is in its lowest excited state, only 120kJmol1 is needed to ionize it. What is the wavelength of the radiation emitted when an atom of X undergoes a transition from the lowest excited state to the ground state?
In the photoelectric effect, electrons are ejected from a metal surface when light strikes it. A certain minimum energy, Emin, is required to eject an electron. Any energy absorbed beyond that minimum gives kinetic energy to the electron. It is found that when light at a wavelength of 540 nm falls on a cesium surface, an electron is ejected with a kinetic energy of 2.601020J. When the wavelength is 400 nm, the kinetic energy is 1.541019J. (a) Calculate Emin for cesium in joules. (b) Calculate the longest wavelength, in nanometers, that will eject electrons from cesium.
What type of relationship (direct or inverse) e xists between wavelength, frequency, and photon energy? What does a photon energy unit of a joule equal?
Imagine a world in which the rule for the l quantum number is that values start with 1 and go up to n. The rules for the n and mi quantum numbers are unchanged from those of our world. Write the quantum numbers for the first two shells (i.e., n = 1 and n = 2).
(a) The nitrogen atom has one electron in each of the 2px , 2py , and 2pz orbitals. By using the form of the angular wave functions, show that the total electron density, 2(2px)+2(2py)+2(2pz) , is spherically symmetric (that is, it is independent of the angles and ). The neon atom, which has two electrons in each 2p orbital, is also spherically symmetric. (b) The same result as in part (a) applies to d orbitals, thus a filled or half-filled subshell of d orbitals is spherically symmetric. Identify the spherically symmetric atoms or ions among the following: F , Na, Si, S2,Ar+ , Ni, Cu, Mo, Rh, Sb, W, Au.