The first step in the extraction of copper metal from its ore is shown below. The numbers beneath each formula are the molar mass, M, (units of grams/mole) and the enthalpy of formation, AfH°, (units of kilojoules/mole) of that substance. 4 CuFeS2(s) + 9 O2(8) → 2 Cu2s (s) + 2 Fe2O3(s) + 6 SO2(8) M/g•mol-1 184 32.0 159 160 64.1 A¢H°(kJ/mol) -197 -80.0 -824 -297 1. What mass of SO2 gas, a source of acid rain, is produced from the reaction of 1234 g of CuFeS2? А. 431 g В. 372 g С. 645 g D. 287 g 2. What volume of O2 gas, measured at 15 °C and 1.00 atm, is required to react with 13.4 mol of CuFeS2? (R = 0.0821 L·atm/mol·K; T/K = T/°C+ 273.) A. 317 L В. 141 L C. 930 L D. 713 L 3. What is the value of the enthalpy change, AH°, for the above reaction? A. -1004 kJ B. +1004 kJ C. -2891 kJ D. -2802 kJ

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Chapter8: Thermochemistry
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The first step in the extraction of copper metal from its ore is shown below. The numbers beneath each
formula are the molar mass, M, (units of grams/mole) and the enthalpy of formation, AfH°, (units of
kilojoules/mole) of that substance.
4 CuFeS2(s) + 9 O2(8)
> 2 СuzS (s) +
2 Fe203(s)
+ 6 SO2(g)
M/g•mol-1
184
32.0
159
160
64.1
A¢H°(kJ/mol)
-197
-80.0
-824
-297
1. What mass of SO2 gas, a source of acid rain, is produced from the reaction of 1234 g of CuFeS2?
A. 431 g
В. 372 g
C. 645 g
D. 287 g
2. What volume of O2 gas, measured at 15 °C and 1.00 atm, is required to react with 13.4 mol of
CuFeS2? (R = 0.0821 L-atm/mol·K; T/K = T/°C + 273.)
А. 317 L
В. 141 L
С. 930 L
D. 713 L
3. What is the value of the enthalpy change, AH°, for the above reaction?
A. -1004 kJ
В. +1004 k]
С. -2891 kJ
D. -2802 kJ
4. Which of the following statements about AS°, the entropy change for the above reaction, is correct?
A. AS° >> 0
В. AS° ~ 0
C. AS° << 0
D. AS° cannot be estimated for this reaction.
Transcribed Image Text:The first step in the extraction of copper metal from its ore is shown below. The numbers beneath each formula are the molar mass, M, (units of grams/mole) and the enthalpy of formation, AfH°, (units of kilojoules/mole) of that substance. 4 CuFeS2(s) + 9 O2(8) > 2 СuzS (s) + 2 Fe203(s) + 6 SO2(g) M/g•mol-1 184 32.0 159 160 64.1 A¢H°(kJ/mol) -197 -80.0 -824 -297 1. What mass of SO2 gas, a source of acid rain, is produced from the reaction of 1234 g of CuFeS2? A. 431 g В. 372 g C. 645 g D. 287 g 2. What volume of O2 gas, measured at 15 °C and 1.00 atm, is required to react with 13.4 mol of CuFeS2? (R = 0.0821 L-atm/mol·K; T/K = T/°C + 273.) А. 317 L В. 141 L С. 930 L D. 713 L 3. What is the value of the enthalpy change, AH°, for the above reaction? A. -1004 kJ В. +1004 k] С. -2891 kJ D. -2802 kJ 4. Which of the following statements about AS°, the entropy change for the above reaction, is correct? A. AS° >> 0 В. AS° ~ 0 C. AS° << 0 D. AS° cannot be estimated for this reaction.
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